用符合正电子湮没辐射Doppler展宽技术研究了La2/3Ca1/3Mn1-xFexO3陶瓷的缺陷和3d电子行为.结果表明:对x≤0.33的样品,随着样品中Fe含量的增加,3d电子数量增加,样品的商谱谱峰升高；对x＞0.50的样品,随着样品中Fe含量的增加,样品中有新相生成,体系缺陷增加,样品的商谱谱峰降低.测试了La2/3Ca1/3Mn1-x-FexO3多晶陶瓷的磁电阻性能,讨论了微观缺陷和3d电子对La2/3Ca1/3Mn1-xFexO3多晶陶瓷磁电阻性能的影响.
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