金属有机骨架(Metal-organic frameworks)材料属于新一代纳米多孔材料,因其具有比表面积大,孔隙率高,结构及功能多样等特点而被广泛应用于气体吸附与分离、传感器、药物缓释、催化反应等领域中.尤其在催化领域,与传统无机材料相比,MOFs因其含有有机配体组分,可以通过有机转化引入各种有机官能团;因其具有多孔性,可以同时实现材料表面与内部的改性,比无机材料只能表面改性更具优势,MOFs作为催化材料为催化领域的发展提供了新的思路.本文综述了MOFs材料作为催化材料的特点和的合成方法以及应用,并对今后的发展进行了展望.
参考文献
| [1] | O. M. Yaghi;Guangming Li.Mutually Interpenetrating Sheets and Channels in the Extended Structure of lCu(4,4'-bpy)Cl][J].Angewandte Chemie,19952(2):207-209. |
| [2] | Hailian Hi;Mohamed Eddaoudi;M.O'Keeffe.Design and synthesis of an exceptionally stable and highly porous metal-organic framework[J].Nature,19996759(6759):276-278. |
| [3] | Richard V. Morris;Steven W. Ruff;Ralf Gellert;Douglas W. Ming;Raymond E. Arvidson;Benton C. Clark;D. C. Golden;Kirsten Siebach;Goestar Klingelhoefer;Christian Schroeder;Iris Fleischer;Albert S. Yen;Steven W. Squyres.Ultrahigh Porosity in Metal-Organic Frameworks[J].Science,2010Jul.23 TN.5990(Jul.23 TN.5990):424-428. |
| [4] | Furukawa, Hiroyasu;Mueller, Ulrich;Yaghi, Omar M.."Heterogeneity within Order" in Metal-Organic Frameworks[J].Angewandte Chemie,201511(11):3417-3430. |
| [5] | Young Kyu Hwang;Do-Young Hong;Jong-San Chang.Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation[J].Angewandte Chemie,200822(22):4144-4148. |
| [6] | Palraj Kasinathan;You-Kyong Seo;Kyu-Eun Shim.Effect of Diamine in Amine-Functionalized MIL-101 for Knoevenagel Condensation[J].Bulletin of the Korean Chemical Society,20116(6):2073-2075. |
| [7] | Yang Yang;Hong-Fei Yao;Fu-Gui Xi.Amino-functionalized Zr(IV) metal-organic framework as bifunctional acid-base catalyst for Knoevenagel condensation[J].Journal of molecular catalysis, A. Chemical,2014:198-205. |
| [8] | Horike, S;Dinca, M;Tamaki, K;Long, JR.Size-selective lewis acid catalysis in a microporous metal-organic framework with exposed Mn2+ coordination sites[J].Journal of the American Chemical Society,200818(18):5854-5855. |
| [9] | Hasegawa S;Horike S;Matsuda R;Furukawa S;Mochizuki K;Kinoshita Y;Kitagawa S.Three-dimensional porous coordination polymer functionalized with amide groups based on tridentate ligand: Selective sorption and catalysis[J].Journal of the American Chemical Society,20079(9):2607-2614. |
| [10] | Wang ZQ;Tanabe KK;Cohen SM.Accessing Postsynthetic Modification in a Series of Metal-Organic Frameworks and the Influence of Framework Topology on Reactivity[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,20091(1):296-306. |
| [11] | Banerjee, M;Das, S;Yoon, M;Choi, HJ;Hyun, MH;Park, SM;Seo, G;Kim, K.Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal-Organic Porous Materials[J].Journal of the American Chemical Society,200922(22):7524-7525. |
| [12] | Michal Sabo;Antje Henschel;Heidrun Frode.Solution infiltration of palladium into MOF-5: synthesis, physisorption and catalytic propertiest[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,200736(36):3827-3832. |
| [13] | Horcajada P;Serre C;Maurin G;Ramsahye NA;Balas F;Vallet-Regi M;Sebban M;Taulelle F;Ferey G.Flexible porous metal-organic frameworks for a controlled drug delivery[J].Journal of the American Chemical Society,200821(21):6774-6780. |
| [14] | Aijaz, A.;Karkamkar, A.;Choi, Y.J.;Tsumori, N.;R?nnebro, E.;Autrey, T.;Shioyama, H.;Xu, Q..Immobilizing highly catalytically active Pt nanoparticles inside the pores of metal-organic framework: A double solvents approach[J].Journal of the American Chemical Society,201234(34):13926-13929. |
| [15] | Klaus Schlichte;Tobias Kratzke;Stefan Kaskel.Improved synthesis,thermal stability and catalytic properties of the metal-organic framework compound Cu_3(BTC)_2[J].Microporous and Mesoporous Materials,20041/2(1/2):81-88. |
| [16] | Zhang, Qiang;Su, Jie;Feng, Dawei;Wei, Zhangwen;Zou, Xiaodong;Zhou, Hong-Cai.Piezofluorochromic Metal-Organic Framework: A Microscissor Lift[J].Journal of the American Chemical Society,201532(32):10064-10067. |
| [17] | Feng, Dawei;Gu, Zhi-Yuan;Chen, Ying-Pin;Park, Jihye;Wei, Zhangwen;Sun, Yujia;Bosch, Mathieu;Yuan, Shuai;Zhou, Hong-Cai.A Highly Stable Porphyrinic Zirconium Metal-Organic Framework with shp-a Topology[J].Journal of the American Chemical Society,201451(51):17714-17717. |
| [18] | Jun Kim;Se-Na Kim;Hoi-Gu Jang.CO2 cycloaddition of styrene oxide over MOF catalysts[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2013:175-180. |
| [19] | 严家其;谈瑛;李勇飞;吴志民;陈蒙;潘浪胜;刘跃进.金属有机框架MIL-100（Cr）和MIL-101（Cr）负载磷钨酸催化合成双酚F[J].化工学报,2015(2):97-104. |
| [20] | Nikki Janssens;Lik H. Wee;Sneha Bajpe.Recovery and reuse of heteropolyacid catalyst in liquid reaction medium through reversible encapsulation in Cu3(BTC)2 metal-organic framework[J].Chemical science,20126(6):1847-1850. |
| [21] | Chen, Yu-Zhen;Xu, Qiang;Yu, Shu-Hong;Jiang, Hai-Long.Tiny Pd@Co Core-Shell Nanoparticles Confined inside a Metal-Organic Framework for Highly Efficient Catalysis[J].Small,20151(1):71-76. |
| [22] | Yang, Qihao;Chen, Yu-Zhen;Wang, Zhiyong U.;Xu, Qiang;Jiang, Hai-Long.One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation[J].Chemical communications,201552(52):10419-10422. |
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