将炭毡浸渍于饱和的HfOCI2·8 H2O乙醇溶液中,经600℃热处理形成HfO2/C复合材料,然后采用热梯度化学气相沉积工艺在2100℃进行致密化和石墨化处理使HfO2转化为HfC而得到碳化铪(HfC)改性、整体炭毡增强的炭/炭(HfC-C/C)复合材料整体喉衬.利用小型固体火箭发动机试车台装置,在7MPa、3200℃烧蚀3s以测定HfC含量对喉衬烧蚀性能的影响.结果表明,HfC质量分数为5.7%的HfC-C/C喉衬线烧蚀率减小了25.2%;HfC质量分数为8.7%的HfC-C/C喉衬线烧蚀率减小了49.6%.同时,当HfC质量分数为5.7%时,HfC-C/C喉衬出现了以恒定线烧蚀率为特征的稳态烧蚀阶段,且该阶段的持续时间随HfC含量的增加而增加.
参考文献
[1] | 苏君明 .炭/炭喉衬材料的研究与发展[J].炭素科技,2001,1(01):6-11. |
[2] | 李贺军.炭/炭复合材料[J].新型炭材料,2001(02):79-80. |
[3] | 刘建军,苏君明,陈长乐.炭/炭复合材料烧蚀性能影响因素分析[J].炭素,2003(02):15-19. |
[4] | T. SOGABE;T. MATSUDA;K. KURODA;Y. HIROHATA;T. HINO;T. YAMASHINA .PREPARATION OF B_4C-MIXED GRAPHITE BY PRESSURELESS SINTERING AND ITS AIR OXIDATION BEHAVIOR[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(12):1783-1788. |
[5] | Wolf R .Boronized and siliconized graphites-material processing and effects on properties[J].Journal of Nuclear Materials,1994,212-215(Part 2):1174-1177. |
[6] | Christopher Norfolk;Alexander Mukasyan;Daniel Hayes .Processing of mesocarbon microbeads to high-performance materials: Part I. Studies towards the sintering mechanism[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(1):11-19. |
[7] | Xiao Bin Hu;Gang Cheng;Bin Yun Zhao;Hui Ming Wang;Ke Ao Hu .Catalytic effect of dopants on microstructure and performance of MCMB-derived carbon Laminaitons[J].Carbon: An International Journal Sponsored by the American Carbon Society,2004(2):381-386. |
[8] | 李淑萍,李克智,李玉龙,袁秦鲁,郭领军,和永岗.冲中击损伤对C/C复合材料烧蚀性能的影响[J].无机材料学报,2008(02):219-222. |
[9] | 李翠艳,李克智,欧阳海波,李贺军.HfC改性炭/炭复合材料的烧蚀性能[J].稀有金属材料与工程,2006(z2):365-368. |
[10] | Haipeng Qiu;Lijun Han;Lang Liu .Properties and microstructure of graphitised ZrC/C or SiC/C composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(5):1021-1025. |
[11] | Garcia-Rosales C.;Ordas N.;Oyarzabal E.;Echeberria J.;Balden M. Lindig S.;Behrisch R. .Improvement of the thermo-mechanical properties of fine grain graphite by doping with different carbides[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2002(Pt.b):1282-1288. |
[12] | G. Wen;Y. Lv;T.Q. Lei .Reaction-formed W_2B_5/C composites with high performance[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(5):1005-1012. |
[13] | Changjun Zhou;William S. Kinman;Paul J. McGinn .The effect of heat-treatment temperature on structure and properties of TiB_2/C composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2007(6):1200-1211. |
[14] | 黄海明,杜善义,吴林志,王建新.C/C复合材料烧蚀性能分析[J].复合材料学报,2001(03):76-80. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%