总结了近十年来可逆加成-断裂链转移聚合技术的制备方法在聚合物分子设计领域的研究进展.首先介绍该方法在制备窄分子量分布的均聚物方面的应用,比较了该方法在溶液和乳液体系中的特点,同时介绍了该方法在制备无规和交替共聚物方面的应用,并着重介绍了制备特殊链结构的共聚物,如嵌段,星形,接枝以及梯度共聚物方面的研究进展.并对今后的研究重点和应用前景作了展望.
参考文献
| [1] | 王平华,张斌,唐龙祥,黄璐,王文英.可逆加成-断裂链转移活性自由基聚合[J].高分子材料科学与工程,2006(05):109-112,116. |
| [2] | Uzulina I.;Claverie J.;Kanagasabapathy S. .Reversible addition fragmentation transfer (RAFT) polymerization in emulsion[J].Macromolecular symposia,2000(0):33-38. |
| [3] | Tian Ying GUO,Dong Lin TANG,Jing Wei ZHU,Mou Dao SONG,Bang Hua ZHANG.RAFT Miniemulsion Polymerization of MMA with Cumyl Dithiobenzoate as Chain Transfer Agent[J].中国化学快报（英文版）,2006(09):1247-1250. |
| [4] | 梁俊,朱秀林,朱健,程振平.苯乙烯与富马酸二甲酯的RAFT无规共聚[J].石油化工,2004(07):666-669. |
| [5] | Fiten MWM;Paulus RM;Schubert US .Systematic parallel investigation of RAFT polymerizations for eight different (meth)acrylates: A basis for the designed synthesis of block and random copolymers[J].Journal of Polymer Science, Part A. Polymer Chemistry,2005(17):3831-3839. |
| [6] | Mark C.Davies;John V.Dawkins;Douglas J.Hourston .Radical copolymerization of maleic anhydride and substituted styrenes by reversible addition-fragmentation chain transfer (RAFT) polymerization[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(6):1739-1753. |
| [7] | 朱明强,魏柳荷,周鹏,杜福胜,李子臣,李福绵.苯甲酸乙烯酯与受电子单体的可逆加成-断链链转移共聚合[J].化学学报,2002(03):551-554. |
| [8] | 庄荣传,陈昊鸿,林建,叶剑良,邹友思.用双硫酯链转移法合成嵌段聚合物[J].高分子学报,2001(03):288-292. |
| [9] | Eberhardt M;Theato P .RAFT polymerization of pentafluorophenyl methacrylate: Preparation of reactive linear diblock copolymer[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2005(18):1488-1493. |
| [10] | Yang C;Cheng YL .RAFT synthesis of Poly(N-isopropylacrylamide) and poly(methacrylic acid) homopolymers and block copolymers: Kinetics and characterization[J].Journal of Applied Polymer Science,2006(2):1191-1201. |
| [11] | Donovan MS.;Lowe AB.;Sanford TA.;McCormick CL. .Sulfobetaine-containing diblock and triblock copolymers via reversible addition-fragmentation chain transfer polymerization in aqueous media[J].Journal of Polymer Science, Part A. Polymer Chemistry,2003(9):1262-1281. |
| [12] | Sumerlin BS.;Lowe AB.;Thomas DB.;McCormick CL. .Aqueous solution properties of pH-responsive AB diblock acrylamido copolymers synthesized via aqueous RAFT[J].Macromolecules,2003(16):5982-5987. |
| [13] | Manguian M;Save M;Charleux B .Batch emulsion polymerization of styrene stabilized by a hydrophilic Macro-RAFT agent[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2006(6):399-404. |
| [14] | Yuan JJ.;Ma R.;Gao Q.;Wang YF.;Cheng SY.;Feng LX.;Fan ZQ.;Jiang L. .Synthesis and characterization of polystyrene/poly(4-vinylpyridine) triblock copolymers by reversible addition-fragmentation chain transfer polymerization and their self-assembled aggregates in water[J].Journal of Applied Polymer Science,2003(4):1017-1025. |
| [15] | 陈卫星,范晓东,刘郁杨,田威.两亲性三嵌段聚合物的合成与表征及分子自组装行为[J].高分子材料科学与工程,2006(03):88-92. |
| [16] | Quinn JF.;Chaplin RP.;Davis TP. .Facile synthesis of comb, star, and graft polymers via reversible addition-fragmentation chain transfer (RAFT) polymerization[J].Journal of Polymer Science, Part A. Polymer Chemistry,2002(17):2956-2966. |
| [17] | Stenzel MH.;Davis TP. .Star polymer synthesis using trithiocarbonate functional beta-cyclodextrin cores (Reversible addition-fragmentation chain-transfer polymerization)[J].Journal of Polymer Science, Part A. Polymer Chemistry,2002(24):4498-4512. |
| [18] | Mayadunne RTA.;Jeffery J.;Moad G.;Rizzardo E. .Living free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization): Approaches to star polymers[J].Macromolecules,2003(5):1505-1513. |
| [19] | Yu-Gang Li;Peng-Jie Shi;Yunshen Zhou;Cai-Yuan Pan .Synthesis and characterization of block comb-like copolymers P(A-MPEO)-block-PSt[J].Polymer international,2004(3):349-354. |
| [20] | Hernandez-Guerrero M;Davis TP;Barner-Kowollik C;Stenzel MH .Polystyrene comb polymers built on cellulose or poly(styrene-co-2-hydroxyethylmethacrylate) backbones as substrates for the preparation of structured honeycomb films[J].European Polymer Journal,2005(10):2264-2277. |
| [21] | Johannes J.Vosloo;Matthew P.Tonge;Christopher M.Fellows;Franck D'Agosto;Ronald D.Sanderson;Robert G.Gilbert .Synthesis of Comblike Poly(butyl methacrylate) Using Reversible Addition-Fragmentation Chain Transfer and an Activated Ester[J].Macromolecules,2004(7):2371-2382. |
| [22] | Luo YW;Liu XZ .Reversible addition-fragmentation transfer (RAFT) copolymerization of methyl methacrylate and styrene in miniemulsion[J].Journal of Polymer Science, Part A. Polymer Chemistry,2004(24):6248-6258. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%