综述了聚丙烯材料耐候性能的影响因素,主要包括主链结构、残留催化剂及外部环境中的光、热、氧及水汽等;系统分析了聚丙烯的老化机理,主要有热氧老化和光氧老化,两者都与自由基链式反应有关;最后概括了改善聚丙烯材料耐候性能的方法,主要是添加有机助剂、无机纳米材料和选择合理的加工方式。
The recent development of weatherability of polypropylene ( PP) materials was reviewed.The factors affecting weatherability of PP were discussed ,including main chain structure ,residual catalyst and external environ-ment.The aging mechanisms of PP such as thermal-oxidative aging and photooxidation aging were analyzed in de-tail.The two aging mechanisms were related to free radical chain reaction.And,this paper generalizes improving weatherability of PP by means of adding organic assistant , adding inorganic nano-materials and selecting suitable processing method.
参考文献
[1] | 钱欣,郑荣华,蔡鹏.聚丙烯的热氧老化及其影响因素[J].浙江工业大学学报,2002(05):475-480. |
[2] | Allen NS.;Corrales T.;Childs A.;Liauw CM.;Catalina F. Peinado C.;Minihan A.;Aldcroft D.;Edge M. .Ageing and stabilisation of filled polymers: an overview[J].Polymer Degradation and Stability,1998(2):183-199. |
[3] | 章陈辉 .阻燃聚丙烯抗老化母粒[P].中国专利,201110231657.5,2011-8-12. |
[4] | Pandey, JK;Reddy, KR;Kumar, AP;Singh, RP .An overview on the degradability of polymer nanocomposites[J].Polymer Degradation and Stability,2005(2):234-250. |
[5] | M. Kato;Z. Osawa .Effect of stereoregularity on the thermo-oxidative degradation of polypropylenes[J].Polymer Degradation and Stability,1999(3):457-461. |
[6] | Tomoyuki Hatanaka;Hideharu Mori;Minoru Terano .Study of thermo-oxidative degradation of molten state polypropylenes with a variety of tacticities[J].Polymer Degradation and Stability,1999(2):313-319. |
[7] | Chen H B;Karger-Kocsis J;Wu J S et al.Frac-ture toughness of α-and β-phase polypropylene homopolymers and random-and block-copolymers[J].POLYMER,43(24):6505-6514. |
[8] | 陶友季,张晓东,麦堪成,左建.不同晶型聚丙烯的光老化行为[J].合成树脂及塑料,2010(04):70-73. |
[9] | 王丹灵,钱欣.紫外照射下聚丙烯结晶结构变化和耐老化性能研究[J].中国塑料,2009(01):51-54. |
[10] | Tidjani A. .PHOTOOXIDATION OF POLYPROPYLENE UNDER NATURAL AND ACCELERATED WEATHERING CONDITIONS[J].Journal of Applied Polymer Science,1997(13):2497-2503. |
[11] | 潘江庆.催化剂残渣对聚丙烯老化性能的影响[J].老化通讯,1978(03):11. |
[12] | 朗比B;拉贝克J F.聚合物的光降解、光氧化和光稳定[M].北京:科学出版社,1986:124. |
[13] | 齐菊英,胡兴洲.三氯化铁对聚丙烯光氧化降解的作用[J].感光科学与光化学,1989(01):18. |
[14] | 王俊,揭敢新.不同自然暴露方法对聚丙烯老化的影响[J].装备环境工程,2005(01):55-58. |
[15] | 胡行俊.紫外光与合成材料的光老化[J].合成材料老化与应用,2006(02):10-13. |
[16] | 王雅珍,鲍红光,李婷玉,兰天宇,张晓宇.助剂改性聚丙烯耐候性研究进展[J].广州化工,2010(01):10-13. |
[17] | 曹民干,苗文俊,李江伟.聚丙烯土工膜的老化因素和防护措施[J].新型建筑材料,2007(06):73-75. |
[18] | D.L.Faulkner.高氧气压和温度对聚丙烯老化的影响[J].老化与应用,1984(03):38. |
[19] | 刘小林.应力作用下的PP光氧降解行为研究[J].塑料科技,2011(08):66-69. |
[20] | Rui Chen;David R.Tyler .Origin of Tensile Stress-Induced Rate Increases in the Photochemical Degradation of Polymers[J].Macromolecules,2004(14):5430-5436. |
[21] | 费正东 .混杂改性聚丙烯热氧老化及机理研究[D].浙江工业大学,2007. |
[22] | 马建忠 .聚丙烯/蒙脱土纳米复合材料老化性能研究[D].兰州理工大学,2007. |
[23] | 李良训;姚琨;聂伟 .纳米材料对聚丙烯抗老化影响及其机理研究[J].金山油化纤,2001,1:14-17. |
[24] | 刘法谦,刘保成,李荣勋,陈桂兰,刘光烨.耐候聚丙烯老化性能的研究[J].中国塑料,2002(05):47-51. |
[25] | 王洪山,郭琛,孙亚斌.酚类抗氧剂及结构优化[J].石油化工应用,2010(07):1-6. |
[26] | 邹志明,章永化,许德雄,蒋智杰,黄汉雄.防老化母料对共聚级聚丙烯的抗紫外老化作用[J].合成材料老化与应用,2000(04):27-30,35. |
[27] | 徐斌,钟明强,孙莉,项赛飞,徐立新.纳米TiO2、纳米ZnO对聚丙烯抗紫外光老化及结晶性能的影响[J].高分子材料科学与工程,2007(01):137-140. |
[28] | 徐立新,钟明强.纳米TiO2对聚丙烯抗紫外老化作用研究[J].浙江工业大学学报,2006(03):302-305. |
[29] | Marco Morreale .The role of filler type In the photo-oxidation behaviour of micro- and nano-filled polypropylene[J].Polymer international,2011(7):1107-1116. |
[30] | Diagne M;Gueye M;Dasilva A;Tidjani A .Comparative photo-oxidation under natural and accelerated conditions of polypropylene nanocomposites produced by extrusion and injection molding[J].Journal of Applied Polymer Science,2007(6):3787-3793. |
[31] | 胡行俊.聚丙烯的光氧老化研究(Ⅰ)[J].合成材料老化与应用,2003(01):1-3. |
[32] | 刘斌,刘庆辉,瞿金平.动态注射成型聚丙烯制品的热氧老化性能[J].高分子材料科学与工程,2009(11):111-114. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%