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(LB)技术,在不同膜压条件下制备了四苯基卟啉锌(ZnTPP)和四苯基卟啉铜(CuTPP)LB膜,分析了两种金属卟啉LB膜分别对吡啶、乙酸乙酯和四氢呋喃气体的紫外-可见光吸收光谱变化,并通过LB膜对紫外-可见光吸收光谱响应的变化,系统研究了两种金属卟啉LB膜的气敏特性,初步建立适合有机气体传感器敏感探测单元使用的材料体系.实验结果表明,在23mN/m的膜压条件下,金属卟啉的成膜效果最好,金属卟啉LB膜的紫外-可见吸收光谱响应最敏感,且发现分别通入3种不同气体后,CuTPP LB膜和ZnTPP LB膜的吸收光谱呈现不同的响应.所以CuTPP LB膜和ZnTPP 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kPa增加到363.8 kPa,内摩擦角由24.4°提高到44.3°,分别提高了210.4%、81.6%;复合改性从微观上改变了软的结构,提高了颗粒间的胶结作用力,并在颗粒表面形成一层憎水膜.","authors":[{"authorName":"王来贵","id":"5b9062c9-b331-4323-af56-9458958c7c73","originalAuthorName":"王来贵"},{"authorName":"张鹏","id":"3af14208-04b0-4a00-bfeb-e5d1beb5555f","originalAuthorName":"张鹏"},{"authorName":"杨建林","id":"0c7c2805-9397-432c-86ae-bb099d560240","originalAuthorName":"杨建林"},{"authorName":"李喜林","id":"072dd77b-f3f8-4ba0-bd54-99f853d07c36","originalAuthorName":"李喜林"}],"doi":"","fpage":"99","id":"d3d8875a-466b-4070-9b71-75e02f526d0e","issue":"1","journal":{"abbrevTitle":"GSYTB","coverImgSrc":"journal/img/cover/GSYTB.jpg","id":"36","issnPpub":"1001-1625","publisherId":"GSYTB","title":"硅酸盐通报 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