在甲醇中用三氯化铋或三氯化锑分别与L-色氨酸(Htrp)和8-羟基喹啉(8-Hhq)合成了三元配合物M(trp)_2(8-hq) [M=Sb(Ⅲ),Bi(Ⅲ)].用元素分析、X射线粉末衍射和红外光谱对三元配合物进行了表征,研究了其热性质和电化学性质.对XRD数据进行了指标化,结果表明:2种三元配合物均属于单斜晶系, Sb(trp)_2(8-hq)的晶胞参数为:a=1.9322 nm,b=2.3938 nm,c=1.8736 nm,β=99.981°;Bi(trp)_2(8-hq)的晶胞参数:a=1.8938 nm,b=1.6168 nm,c=1.0482 nm,β=95.020°.
参考文献
| [1] | Cantos G;Barbieri C L;Iacomini M et al.Synthesis of Antimony Complexes of Yeast Mannan and Mannan Derivatives and Their Effect on Leishmania-infected Macrophages[J].Biochemical Journal,1993,289:155-160. |
| [2] | 胡盛志,林文锋.丙二胺四乙酸锑（Ⅲ）的晶体结构与抗肿瘤活性络合物的结构化学研究[J].结构化学,1989(04):249. |
| [3] | Lecureur V;Lagadic Gossmann D;Fardel O .Potassium antimonyl tartrate induces reactive oxygen species-related apoptosis in human myeloid leukemic HL60 cells.[J].International journal of oncology,2002(5):1071-1076. |
| [4] | Lecureur V;Le T A;Le M A et al.Potassium Antimonyl Tartrate Induces Caspase-and Reactive Oxygen Species-dependent Apoptosis in Lymphoid Tumoral Cells[J].British Journal of Haematology,2002,119(03):608-615. |
| [5] | 于文强,孙秉中,柴玉波,赵忠良,刘雪松,纪宗玲,路凡,陈苏民.不同锑剂对早幼粒细胞白血病凋亡诱导作用比较[J].第四军医大学学报,2003(04):338-341. |
| [6] | Briand Glen G.;Burford Neil .Bismuth Compounds and Preparations with Biological or Medicinal Relevance[J].Chemical Reviews,1999(9):2601-2657. |
| [7] | Sun HZ.;Szeto KY. .Binding of bismuth to serum proteins: implication for targets of Bi(III) in blood plasma[J].Journal of Inorganic Biochemistry: An Interdisciplinary Journal,2003(1/2):114-120. |
| [8] | Sun H Z;Szeto K Y;Zhang L .Bismuth in Medicine[J].Metal Ions In Biological Systems,2004,41:338-378. |
| [9] | 孙红哲,张丽,司徒嘉怡.含铋类药物的生物化学和药物化学研究进展[J].中国临床药理学杂志,2002(04):297-301. |
| [10] | Wang X;Zhang X;Lin J.DNA-binding Property and Antitumor Activity of Bismuth Complex with 1,4,7,10-tetrakis (2-pyridylmethyl)-1,4,7,10-tetraazacyclo Dodecane[J].Journal of the Chemical Society,Dalton Transactions,2003(12):2379-2380. |
| [11] | Tiekink E R T .Antimony and Bismuth Compounds in Oncology[J].Critical Reviews in Oncology/Hematology,2002,42:217-224. |
| [12] | 褚泰伟,谢景林,王祥云.色氨酸、组氨酸羰基锝配合物的制备及其在荷S180瘤小鼠体内的分布[J].核技术,2002(05):361-366. |
| [13] | 陈亮,钞建宾,续浩,楼新锋.色氨酸与稀土元素Eu（Ⅲ）配合物的合成及配位位置的研究[J].波谱学杂志,2001(01):31-40. |
| [14] | 蒋琪英,陈明剑,胡亚敏,沈娟,钟国清.8-羟基喹啉铋的合成、表征与光谱研究[J].化学研究与应用,2008(01):58-61. |
| [15] | 中本一雄;黄德如;汪仁庆.无机和配位化合物的红外和拉曼光谱[M].北京:化学工业出版社,1986 |
| [16] | 翁诗釜.傅立叶变换红外光谱仪[M].北京:化学工业出版社,2005:249. |
| [17] | 吴惠霞,王则民,杨海峰,余锡宾.稀土烟酸与8-羟基喹啉三元配合物的合成、表征及荧光光谱[J].中国稀土学报,2002(04):289-292. |
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