采用醋酸有机酸分离法对油页岩灰渣中的金属元素进行转化分离,利用醋酸的高选择性和低污染性,将Ca、Mg、Na、K等金属元素转化为醋酸盐,实现高效分离.采用Tessier法和BCR法研究油页岩灰渣中金属元素的赋存状态,结果表明,油页岩灰渣中Ca、Mg、Na、K四种元素主要以可交换态、碳酸盐结合态和氧化物结合态等醋酸可提取态赋存,适于醋酸浸取分离法;而Fe元素的赋存状态不是醋酸可提取态,仅有少量以氧化物结合态赋存,不适于醋酸浸取分离法.研究了不同反应条件(反应时间、反应温度和醋酸浓度)对油页岩灰渣中金属元素醋酸浸出率的影响规律,优化反应条件可提高其醋酸浸出率,选择醋酸浓度为30%,醋酸浸取反应温度为30℃,反应时间为2.0h.
参考文献
[1] | Qian Jialin;Yin Liang.Oil Shale-Petroleum alternative[M].北京:中国石化出版社,2010:360. |
[2] | Sedman A;Talviste P;Kirsimae K .The study of hydration and carbonation reactions and corresponding changes in the physical properties of co-depositend oil shale ash and semicoke wastes wastes in a small-scale field experiment[J].Oil Shale,2012,29(03):279. |
[3] | 冯宗玉,李勇,薛向欣,贺燕,刘平先.利用油页岩渣制备氧化铝和白炭黑[J].矿冶工程,2008(04):53-57. |
[4] | Y.-M, XU;D.-M. HE;J.-W. SHI .PREPARATION OF ALUMINA FROM RETORTING RESIDUE OF OIL SHALE[J].Oil Shale,2012(1):36-50. |
[5] | XU YING-MEI;QI JI;SHI JIA-WEI .TECHNIQUE OF PREPARING MODIFIED SILICA FROM OIL SHALE RESIDUE[J].Oil Shale,2011(2):309-320. |
[6] | Xu Yingrnei et al.Preparation of amorphous silica from oil shale residue and surface modification by silane coupling agent[J].Oil Shale,2010,27(01):37. |
[7] | Gao Guimei et al.Preparation and properties of silica nanoparticles from oil shale ash[J].Powder Technology,2009,191(1-2):47. |
[8] | Ahmaruzzaman M .Role of fly ash in the removal of organic pollutants from wastewater[J].Energy and Fuels,2009,23(03):1494. |
[9] | Fatima Arroyo;Constantino Fernandez-Pereira;Joaquin Olivares .Hydrometallurgical Recovery of Germanium from Coal Gasification Fly Ash:Pilot Plant Scale Evaluation[J].Industrial & Engineering Chemistry Research,2009(7):3573-3579. |
[10] | Lu S G;Chen Y Y et al.Mineralogy and heavy metal leachability of magnetic fractions separated from some Chinese coal fly ashes[J].Journal of Hazardous Materials,2009,169(1-3):246. |
[11] | Wang Tian;Wang Jiaumin;Tang Yulin et al.Leaching characteristics of arsenic and selenium from coal fly ash:Role of calcium[J].Energy and Fuels,2009,23(06):2959. |
[12] | Tessier A;Campbell P G C;Bisson M .Sequential extraction procedure for the speciation of particulate trace metals[J].Analytical Chemistry,1979,51(07):844. |
[13] | 许英梅,张秋民,姜慧明,张树彪.由木醋液制醋酸钙镁盐类环保型融雪剂研究[J].大连理工大学学报,2007(04):494-496. |
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