以聚(甲基丙烯酸甲酯-丙烯腈)共聚物为凝胶电解质基体,取代传统的液体电解质制备准固态染料太阳能电池.该太阳能电池表现出了较好的光电性能,经过优化后,这种凝胶电解质的最高室温电导率可达到4.38 mS·cm-1.该电解质组装的太阳能电池在100 mW/cm2(AM1.5)的模拟光照下,短路电流、开路电压、填充因子、光电转换效率分别为:12.6 mA·cm-2、750 mV、0.53、5.02%.
参考文献
[1] | Graitzel MJ .[J].Nature,1991,353(04):737. |
[2] | Hitoshi N A;Hironori A .[J].Journal of Photochemistry and Photobiology A:Chemistry,2004,165:157. |
[3] | Fellieien;Mazille et al.[J].Inorganic Chemistry,2006,45:1585. |
[4] | Hitoshi N A;Hironori A .[J].Journal of Photochemistry and Photobiology A:Chemistry,2004,164:103. |
[5] | NAambe S;NaNaade S;NAitamura T et al.[J].Journal of Physical Chemistry B,2002,106(11):2967. |
[6] | NAubo W;MuraNaoshi N A;NAitamura T .[J].Journal of Physical Chemistry B,2001,105:12809. |
[7] | NAubo W;NAambe S;NaNaade S et al.[J].Journal of Physical Chemistry B,2003,107:4374. |
[8] | Sapp SA.;Elliott CM.;Contado C.;Caramori S.;Bignozzi CA. .Substituted polypyridine complexes of cobalt(II/III) as efficient electron-transfer mediators in dye-sensitized solar cells[J].Journal of the American Chemical Society,2002(37):11215-11222. |
[9] | Wang P;ZaNaeeruddin S M;Comte P et al.[J].Journal of the American Chemical Society,2003,125:1166. |
[10] | 兰章 .准固态染料敏化太阳能电池的研究[D].泉州:华侨大学,2006. |
[11] | Gratzel M .[J].Journal of Photochemistry and Photobiology A:Chemistry,2004,164:3. |
[12] | 校峰 .PAMMA共聚乳液的制备与应用[D].西安:西北工业大学,2007. |
[13] | 杨宏训 .染料敏化TiO2太阳能电池中聚合物凝胶电解质的研究[D].泉州:华侨大学,2007. |
[14] | Burnside SD.;Barbe C.;Comte P.;Arendse F.;Brooks K. Gratzel M.;Shklover V. .Self-organization of TiO2 nanoparticles in thin films[J].Chemistry of Materials,1998(9):2419-2425. |
[15] | Graitzel M .[J].Progress in Photovoltaics:Research and Applications,2000,8:171. |
[16] | 郭炳坤;徐徽;王先友.锂离子电池[M].长沙:中南大学出版社,2002 |
[17] | Kalyanasundaram K;Gratzel M .[J].Coordination Chemistry Reviews,1998,177:347. |
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