运用X射线衍射、扫描电镜及粒度分析等方法表征了机械合金化制备Mg/MmNi5-x(CoAlMn)x复合储氢合金的结构,通过PCT曲线研究了其储氢性能.结果表明,在适当的球磨条件下能够获得纳米晶结构的Mg/MmNi5-x(CoAlMn)x复合储氢合金,与MmNi5-x(CoAlMn)x合金相比,复合储氢合金的活化性能及储氢量有明显提高.此外,还考察了Mg含量对复合储氢合金的组织结构及储氢性能的影响.
参考文献
| [1] | Zaluski L;Zaluska A;Strom-Olsen J O .Nanocrystalline metal hydrides[J].Journal of Alloys and Compounds,1997,253-254:70. |
| [2] | Kronberger H .Nanocrystalline hydrogen storage alloys for rechargeable batteries[J].Journal of Alloys and Compounds,1997,253-254:87. |
| [3] | Ivanov E;Konstanchuk I;Stepanov A et al.Magnesium mechanical alloys for hydrogen storage[J].Journal of THE LESS-COMMON METALS,1987,131:25. |
| [4] | Au Ming;Pourarian F;Shimizu S et al.Electrochemical propeties of TiMn2-type alloys ball-milled with nickel powder[J].Journal of Alloys and Compounds,1995,223:1. |
| [5] | Liang Guoxian;Wang Erde;Fang Shoushi .Hydrogen absorption and desorption characteristics of mechanically milled Mg-35wt%FeTi1.2 powders[J].Journal of Alloys and Compounds,1995,223:111. |
| [6] | 张海峰;吕曼祺;胡壮麒 等.难活化储氢材料钒的表面改性[J].金属学报,1994,30(10):B459. |
| [7] | Gross K J;Spatz P;Zuttel A et al.Mechanically milled Mg composites for hydrogen storage-the transition to a steady state composition[J].Journal of Alloys and Compounds,1996,240:206. |
| [8] | Nagai H;Tomizawa H;Ogasawara T et al.Hydriding characteristics of Mg-xwt.% LaNi5 sintered alloys[J].Journal of the Less-Common Metals,1990,157:15. |
| [9] | 高岩;罗堪昌;李柏林 等.Ti-Fe二元系在机械合金化过程中的结构及纳米晶Ti-Fe储氢合金的制备[J].功能材料,1998,29(03):256. |
| [10] | Benjamin J S .Mechanical alloying[J].Scientific American,1976,234(05):40. |
| [11] | Klug H P;Alexander L.X-ray Diffraction Procedures for Polycrystalline and Amorphous Materials[M].New York:Wiley Press,1974:661. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%