介绍了近年来环境友好阻燃聚苯乙烯( PS)的研究进展，分别从反应型阻燃剂和添加型阻燃剂展开阐述。反应型阻燃剂相对于添加型阻燃剂能为PS提供更高的阻燃效率和力学性能，并提出无卤、高效、低烟、低毒、多功能的新型PS阻燃材料的研究开发将是当今的发展方向。
The latest research progress of environment-friendly flame retardants for polystyrene ( PS) was intro-duced ,including reactive and additive flame retardants. Reactive flame retardants provide higher efficiency and me-chanical properties for PS. In the long run,halogen-free,high-efficient,low smoke,low toxic or novel fire-retardant PS will be a developing trend in the future.
参考文献
| [1] | Marco Zanetti,Giovanni Camino,Domenico Cana-vese, Alexander B Morgan, Frank K Lamelas, Charles Wilkie . Fire retardant halogen-antimony-clay synergism in polypropylene layered silicate nanocomposites[J].Chemistry of Materials,2002,14(1):189-193.,2002. |
| [2] | Wang Dongyan,Echols Kandice,Wilkie Charles A. Cone calorimetric and thermogravimetric analysis evaluation of halogen-containing polymer nano-composites [J]. Fire and Materials, 2005, 29(5):283-294.,2005. |
| [3] | Hu Yuan,Wang Shaofeng,Ling Zhihua,Zhuang Yonglong, Chen Zuyao, Fan Weicheng . Prepara-tion and combustion properties of flame retardant nylon 6/montmorillonite nanocomposite[J].Mac-romolecular Materials and Engineering,2003,288(3):272-276.,2003. |
| [4] | Morgan Alexander B . Flame retarded polymer lay-ered silicate nanocomposites:a review of commer-cial and open literature systems[J].Polymers for Advanced Technologies,2006,17(4):206-217.,2006. |
| [5] | Song Lei,Hu Yuan,Lin Zhihua,Xuan Shanyong, Wang Shaofeng, Chen Zuyao, et al . Perparation and properties of halogen-free flame-retarded pol-yamide 6/organoclay nanocomposite[J].Polymer Degradation and Stability,2004,86 |
| [6] | Hu Yuan, Tang Yong, Song Lei . Poly(propyl-ene)/clay nanocomposites and their application in flame retardancy[J].Polymers for Advanced Technologies,2006,17(4):235-245.,2006. |
| [7] | 谢芳宁,袁慧根,潘仁云 . 阻燃聚苯乙烯的合成[J].合成树脂及塑料,1995,12(2):16-19.,1995. |
| [8] | Bob A. Howell,Joel Uzibor. Pentaphenyl-1,3, 2-dioxaphospholane as a reactive flame retardant [J]. Journal of Vinyl & Additive Technology, 2006(12):192-197.,2006. |
| [9] | Price D,Bullett K. J,Cunliffe L. K,Hull T. R,et al . Cone calorimetry studies of polymer systems flame retarded by chemically bonded phosphorus[J].Polymer Degradation and Stability,2005,88(1):74-79.,2005. |
| [10] | Tai Qilong,Chen Lijuan,Song Lei,Nie Shibin, Hu Yuan . Preparation and thermal properties of a novel flame retardant copolymer[J].Polymer Degradation and Stability,2010,95(5):830-836.,2010. |
| [11] | 鹿海军,马晓燕,颜红侠.磷系阻燃剂研究新进展[J].化工新型材料,2001(12):7-10. |
| [12] | 何敏,徐定红,粟多文,张家宝,薛斌.红磷母粒与氢氧化镁协效阻燃高抗冲击强度聚苯乙烯研究[J].塑料工业,2011(07):43-45. |
| [13] | 李秀云,唐安斌,郑明嘉,刘德春.磷系阻燃剂生产无卤阻燃高抗冲聚苯乙烯试验[J].西南科技大学学报(自然科学版),2005(04):17-19. |
| [14] | Cui Wenguang,Guo Fen,Chen Jianfeng. Flame retardancy and toughening of high impact poly-styrene [J]. Polymer Composites, 2007, 28:551-559.,2007. |
| [15] | 贾娟花,苑会林,邵晶鑫.聚苯乙烯的无卤阻燃研究[J].合成树脂及塑料,2006(02):36-38. |
| [16] | Lu Hongdian,Wilkie Charles A . Study on intu-mescent flame retarded polystyrene compos-ites with improved flame retardancy[J].Polymer Degradation and Stability,2010,95 |
| [17] | 张昌洪,聂刚,陈宁,等 . 一种磷腈化合物的合成及其PS无卤阻燃体系中的应用[J].中国塑料,2004,18(2):80-85.,2004. |
| [18] | 田秀娟.非卤阻燃剂阻燃聚苯乙烯的研究进展[J].科技信息,2011(28):8. |
| [19] | Hu Yonghua, Han Xu, Tan Rui, Li Shufen . Effects of magnesium hydroxide on combustion pruducts of polystyrene[J].Chinese Journal of Chemical Physics,2007,20(2):185-190.,2007. |
| [20] | 郭锡坤,刘庆大.高抗冲聚苯乙烯的非卤阻燃消烟研究[J].塑料科技,1994(01):6-9. |
| [21] | Chang Suqin, Xie Tingxiu, Yang Guisheng . Effects of polystyrene-encapsulated magnesium hydroxide on rheological and flame-re-rarding properties of HIPS composites[J].Polymer Deg-radation and Stability,2006,91 |
| [22] | Chang Suqin, Xie Tingxiu, Yang Guisheng . Effects of shell thickness of polystyrene-encapsu-lated Mg(OH)2 on flammability and rheological properties of high-impact polystyrene composites[J].Polymer International,2007,56 |
| [23] | Chang Suqin, Xie Tingxiu, Yang Guisheng. Effects of interfacial modification on the thermal, mechanical, and fire properties of high-im-pact polystyrene/microencapsulated red phosphorous [J]. Journal of Applied Polymer Science,2008, 110:2139-2144.,2008. |
| [24] | 王路明.阻燃型氢氧化镁表面改性及与PS复合效果研究[J].无机盐工业,2011(12):29-31. |
| [25] | 杨振,雷新荣,胡明安.聚合物/粘土纳米复合材料制备研究现状[J].矿产保护与利用,2005(02):26-30. |
| [26] | 单雪影,台启龙,胡源,宋磊,袁国杰,卢兆明.本质阻燃聚苯乙烯/蒙脱土纳米复合物的制备及性能[J].高等学校化学学报,2013(10):2431-2436. |
| [27] | Isitman N A,Kaynak C . Tailoredflame retardancy via nanofiller dispersion state:Synergistic action-between a conventionalflame-retardant and nano-clay in high-impact polystyrene[J].Polymer Deg-radation and Stability,2010,95 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%