为综合利用固体废弃物铁尾矿,以山西灵丘低硅铁尾矿作为主要原料,铝粉作为发气剂,成功制备出了符合GB/T11968—2006标准的A3.5、B06级加气混凝土.考虑最大限度使用铁尾矿的情况下,通过试验得出生产铁尾矿加气混凝土的优化方案:尾矿粉磨时间25 min,硅砂粉磨时间为30 min,配料质量比为m(铁尾矿)∶m(硅砂)∶m(石灰)∶m(水泥)∶m(脱硫石膏)为40∶20∶24∶10∶6.由X射线衍射测试分析可知,成品中主要的矿物成分为托贝莫来石,此外还有硬石膏和尾矿中残留的石英等.扫描电镜和能谱分析结果显示,成品中形成C-S-H凝胶和托贝莫来石相互致密交织的显微结构,这是加气混凝土获得较高强度的重要原因.
For comprehensive utilization of iron ore tailings,the aerated concrete was successfully prepared by Shanxi Lingqiu low-silica iron ore tailings as the main raw material and aluminum powder as gas evolution agent,which is in line with GB/T11968—2006 of the A3.5 B06-class.In the case of the maximize use of iron ore tailings,the optimized plan of aerated concrete production was that the iron ore tailings grinding time was 25 min,silica sand grinding time was 30 min,burdening mass ratio of iron ore tailings,silica sand,lime cement and gypsum was 40∶ 20∶ 24∶ 10∶ 6.The major mineral phases in the aerated concrete product were tobermorite with residue quartz and anhydrite.SEM and EDS results showed that the finished product to form bense microstructure by C-S-H gel and tobermorite,it was important reason that aerated concrete obtained high strength.
参考文献
[1] | 张国强 .黄金尾矿在水泥中的资源化利用研究[D].苏州大学,2009. |
[2] | 张淑会,薛向欣,金在峰.我国铁尾矿的资源现状及其综合利用[J].材料与冶金学报,2004(04):241-245. |
[3] | 李德忠,倪文,王长龙,耿碧瑶.不同养护条件对铁尾矿加气混凝土性能的影响[J].新型建筑材料,2011(08):22-24,36. |
[4] | I. Licsko;L. Lois;G. Szebenyi .Tailings as a source of environmental pollution[J].Water Science and Technology,1999(10/11):333-336. |
[5] | 郭建平,吴甫成,谢淑容,姚玲玲,谢玉华.湖南临湘铅锌矿尾矿库环境状况及开发利用研究[J].土壤通报,2007(03):553-557. |
[6] | N. Narayanan;K. Ramamurthy .Microstructural investigations on aerated concrete[J].Cement and Concrete Research,2000(3):457-464. |
[7] | N. Narayanan;K. Ramamurthy .Structure and properties of aerated concrete: a review[J].Cement & concrete composites,2000(5):321-329. |
[8] | 郑永超,倪文,徐丽,李德忠,杨菁华.铁尾矿的机械力化学活化及制备高强结构材料[J].北京科技大学学报,2010(04):504-508. |
[9] | 李方贤,陈友治,龙世宗.用铅锌尾矿生产加气混凝土的试验研究[J].西南交通大学学报,2008(06):810-815. |
[10] | 黄晓燕,倪文,祝丽萍,王中杰.齐大山铁尾矿粉磨特性[J].北京科技大学学报,2010(10):1253-1257. |
[11] | 张志杰,柯昌君,刘平安,钟明峰.硅质固体废物蒸压反应活性的红外光谱研究[J].分析测试学报,2010(01):68-72. |
[12] | 李德忠,倪文,张静文,吴辉,张玉燕.铁尾矿在蒸压养护过程中的物相变化[J].硅酸盐学报,2011(04):708-713. |
[13] | 李子成,李志宏,张爱菊,邱树恒,朱玉梅.α-半水石膏基复合胶凝材料体系微观结构分析[J].稀有金属材料与工程,2008(z1):307-310. |
[14] | 吴笑梅,樊粤明.粉煤灰加气混凝土水化产物的种类和微观结构[J].华南理工大学学报(自然科学版),2003(08):57-61. |
[15] | 王长龙,倪文,李德忠,耿碧瑶,吴辉.山西灵丘低硅铁尾矿制备加气混凝土的试验研究[J].煤炭学报,2012(07):1129-1133. |
[16] | 黄晓燕,倪文,王中杰,钱嘉伟,祝丽萍.铜尾矿制备无石灰加气混凝土的试验研究[J].材料科学与工艺,2012(01):11-15. |
[17] | Xiao-yan Huang;Wen Ni;Wei-hua Cui;Zhong-jie Wang;Li-ping Zhu .Preparation of autoclaved aerated concrete using copper tailings and blast furnace slag[J].Construction and Building Materials,2012(1):1-5. |
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