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利用新的接枝方法——溶剂热合成的方法制备了顺丁烯二酸二丁酯(DBM)接枝乙烯-辛烯共聚物(POE).经傅立叶红外光谱(FT-IR)分析,证明DBM成功地接枝到了POE上,并用-C=O-和-CH2-吸收峰面积的比值来确定相对接枝量的大小.研究了单体DBM含量、引发剂过氧化二异丙苯(DCP)含量和反应温度对接枝反应的影响,找到了合适的反应配比和反应条件,得到了较高接枝率的接枝共聚物.结果表明,溶剂热合成法是将DBM接枝到POE上的一种好方法.

参考文献

[1] 刘亚庆,吕孟海,肖鹏.POE与马来酸酐的反应挤出接枝[J].工程塑料应用,2001(10):17-19.
[2] Yin J;Zhang Y;Zhang YX .Fracture behavior and deformation mechanism of polypropylene/ethylene-octene copolymer/magnesium hydroxide ternary phase composites[J].Journal of Applied Polymer Science,2005(3):957-967.
[3] 张金柱.新型热塑性弹性体POE的性能及其在PP增韧改性中的应用[J].塑料科技,1999(02):5-7.
[4] Kim SJ.;Kang CJ.;Chowdhury SR.;Cho WJ.;Ha CS. .Reactive compatibilization of the poly(butylene terephtalate)-EVA blend by maleic anhydride. II. Correlations among gel contents, grafting yields, and mechanical properties[J].Journal of Applied Polymer Science,2003(5):1305-1310.
[5] Aghjeh MKR;Nazockdast H;Assempour H .Parameters affecting the free-radical melt grafting of maleic anhydride onto linear low-density polyethylene in an internal mixer[J].Journal of Applied Polymer Science,2006(1):141-149.
[6] Li CQ.;Zhang Y.;Zhang YX.;Zhang CM. .Blends of polycarbonate and ethylene-1-octylene copolymer[J].European Polymer Journal,2003(2):305-311.
[7] Jia SW;Xu DC;Bi YM;Ming QZ;Min ZR .Localized compatibilization in immiscible blends of thermoplastic polyurethane and ethylene-octylene copolymer[J].Journal of Applied Polymer Science,2007(3):1309-1315.
[8] Yu ZZ.;Qi ZN.;Hu GH.;Ou YC. .Toughening of nylon 6 with a maleated core-shell impact modifier[J].Journal of Polymer Science, Part B. Polymer Physics,1998(11):1987-1994.
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