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作为一种非硅基介孔材料,介孔金属氧化物在工业催化、光电领域及太阳能电池等领域有着潜在的应用价值.从制备、分类、制备过程中面临的问题以及其应用领域等方面对近年来介孔金属氧化物的研究进展作了总结,指出目前介孔金属氧化物的研究中存在的主要难点是如何提高热稳定性、孔壁的结晶性及介孔的长程有序性.

As a kind of non-siliceous mesoporous material, mesoporous metal oxides have potential application in industrial catalysis, photoelectronic,solar cell and so on. In this article, the synthesis method, category, the main difficulties existing in synthesis and the application area of mesoporous metal oxides are reviewed. It's pointed out that the main problem in mesoporous metal oxides research is how to improve the stability, hole-wall crystallization and long-range order properties.

参考文献

[1] Kresge C T;Leonowicz M E;Roth W J et al.Ordered mesoporous molecular-sieves synthesized by a liquid-crystal template mechanism[J].Nature,1992,359:710.
[2] Roggenbuck J;Schafer H;Tsoncheva T;Minchev C;Hanss J;Tiemann M .Mesoporous CeO2: Synthesis by nanocasting, characterisation and catalytic properties[J].Microporous and mesoporous materials: The offical journal of the International Zeolite Association,2007(3):335-341.
[3] Shyue J J;Guire M R .Single-step preparation of mesoporous anatase-based titanium-vanadium oxide and its application[J].Journal of the American Chemical Society,2005,127:12736.
[4] Sinha A K;Suzuki K .Preparation and characterization of novel mesoporous ceria-titania[J].Journal of Physical Chemistry B,2005,109:1708.
[5] Jiao F;Harrison A;Jumas JC;Chadwick AV;Kockelmann W;Bruce PG .Ordered mesoporous Fe2O3 with crystalline walls[J].Journal of the American Chemical Society,2006(16):5468-5474.
[6] Chen Fanglin;Liu Meilin .Preparation of mesoporous tin oxide for electrochemical applications[J].Chemical communications,1999(18):1829-1830.
[7] Srivastava DN.;Chappel S.;Palchik O.;Zaban A.;Gadanken A. .Sonochemical synthesis of mesoporous tin oxide[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(10):4160-4164.
[8] Wang Y Q;Yang C M;Schmidt W et al.Weakly ferromagnetic ordered mesoporous Co_3O_4 synthesized by nanocasting from vinyl-functionalized cubic Ia3d mesoporous silica[J].Advanced Materials,2005,17:53.
[9] Polarz S;Orlov A V et al.Preparation of high-surface-area zinc oxide with ordered porosity,different pore sizes,and nanocrystalline walls[J].Chemistry-A European Journal,2007,13:592.
[10] Roggenbuck J et al.Ordered mesoporous magnesium oxide with high thermal stability synthesized by exotemplating using CMK-3 carbon[J].Journal of the American Chemical Society,2005,127:1096.
[11] Xing W;Li F;Yan Z F et al.Synthesis and electrochemical properties of mesoporous nickel oxide[J].Journal of Power Sources,2004,134:324.
[12] Fattakhova-Rohlfing D;Wark M;Brezesinski T;Smarsly BM;Rathousky J .Highly organized mesoporous TiO2 films with controlled crystallinity: A Li-insertion study[J].Advanced functional materials,2007(1):123-132.
[13] Wang YD;Ma CL;Sun XD;Li HD .Synthesis and characterization of ordered hexagonal and cubic mesoporous tin oxides via mixed-surfactant templates route[J].Journal of Colloid and Interface Science,2005(2):627-631.
[14] 李斌,王剑华,郭玉忠.分子模板法合成介孔氧化锡[J].功能材料,2007(03):502-504,508.
[15] Sinha AK;Suzuki K .Novel mesoporous chromium oxide for VOCs elimination[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(26):417-422.
[16] 赵旭,罗来涛,刘成文,李茂康.纳米介孔CeO2的合成及表征[J].材料导报,2006(z2):50-52,57.
[17] Lee B.;Yamashita T.;Lu DL.;Kondo JN.;Domen K. .Single-crystal particles of mesoporous niobium-tantalum mixed oxide[J].Chemistry of Materials,2002(2):867-875.
[18] Kirszensztejn P;Przekop R;Szymkowiak A et al.Preparation of MgO-Al_2O_3 binary gel system with mesoporous structure[J].Microporous and Mesoporous Materials,2006,89:150.
[19] Carreon MA;Guliants VV;Yuan L;Hughett AR;Dozier A;Seisenbaeva GA;Kessler VG .Mesoporous nanocrystalline mixed metal oxides from heterometallic alkoxide precursors: Cobalt-nickel oxide spinels for propane oxidation[J].European journal of inorganic chemistry,2006(24):4983-4988.
[20] 张雪红,唐星华,程新孙.TiO2-CeO2介孔复合氧化物的合成及应用[J].物理化学学报,2006(05):532-537.
[21] 陶俊超,孙艳,徐建,王虎,陈鑫,戴宁.介孔TiO2-ZnO复合薄膜的制备与表征[J].高等学校化学学报,2008(09):1880-1884.
[22] 王希涛,贺忠,钟顺和.介孔复合半导体NiO-TiO2的制备与光响应性能[J].无机材料学报,2009(02):215-220.
[23] 郭建维,黄阳海,刘卅,邓志城,余林.有序介孔金属氧化物研究进展[J].材料工程,2007(09):74-80.
[24] 王燕刚,王遥俊,李常林,刘晓晖,王艳芹,卢冠忠.介孔金属氧化物/复合物的合成方法[J].化学进展,2006(10):1338-1344.
[25] 刘超,成国祥.模板法制备介孔材料的研究进展[J].离子交换与吸附,2003(04):374-384.
[26] Shibata H;Mihara H;Mukai T et al.Preparation and formation mechanism of mesoporous titania particles having crystalline wall[J].Chemistry of Materials,2006,18:2256.
[27] Kondo J N et al.Synthesis,mesostructure,and phtocatalysis of a highly ordered and thermally stable mesoporous Mg and Ta mixed oxide[J].CHEMISTRY OF MATERIALS,2004,16:4304.
[28] Yuan Z Y;Ren T Z;Su B L .Surfactant mediated nanopar-ticle assembly of catalytic mesoporous crystalline iron oxide materials[J].Catalysis Today,2004,93-5:743.
[29] Liu B;Baker T .Factors affecting the preparation of ordered mesoporous ZrO_2 using the replica method[J].Journal of Materials Chemistry,2008,18:5200.
[30] Roggenbuck J;Koch G;Tiemann M .Synthesis of mesoporous magnesium oxide by CMK-3 carbon structure replication[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(17):4151-4156.
[31] Deng W H;Toepke M W;Shanks B H .Surfactant-assisted synthesis of alumina with hierarchical nanopores[J].Advanced Functional Materials,2003,13:61.
[32] Liu P et al.Mesostructured vanadium oxide containing do-decylamine[J].Chemistry of Materials,1997,9:2513.
[33] TIAN Z.-R.;TONG W.;WANG J.-Y.;DUAN N.-G.;KRISHNAN V. V.;SUIB S. L. .MANGANESE OXIDE MESOPOROUS STRUCTURES - MIXED-VALENT SEMICONDUCTING CATALYSTS[J].Science,1997(5314):926-930.
[34] Xiaoyong Lai;Xiaotian Li;Wangchang Geng .Ordered Mesoporous Copper Oxide with Crystalline Walls[J].Angewandte Chemie,2007(5):738-741.
[35] Lee B et al.Three-dimensional ordered mesoporous niobium oxide[J].Journal of the American Chemical Society,2002,124:11256.
[36] Chen J L et al.Ordered mixed-valent mesoporous molybdenum oxides[J].Journal of the American Chemical Society,2005,127:14140.
[37] Liu P;Liu J;Sayari A .Preparation of porous hafnium oxide in the presence of a cationic surfactant[J].Journal of the Chemical Society,Chemical Communications,1997,6:577.
[38] S. C. Laha;R. Ryoo .Synthesis of thermally stable mesoporous cerium oxide with nanocrystalline frameworks using mesoporous silica templates[J].Chemical communications,2003(17):2138-2139.
[39] Pavasupree S;Suzuki Y;Pivsa-Art S;Yoshikawa S .Preparation and characterization of mesoporous TiO2-CeO2 nanopowders respond to visible wavelength[J].International Journal of Quantum Chemistry,2005(1):128-134.
[40] Schattka JH.;Shchukin DG.;Jia JG.;Antonietti M.;Caruso RA. .Photocatalytic activities of porous titania and titania/zirconia structures formed by using a polymer gel templating[J].Chemistry of Materials,2002(12):5103-5108.
[41] Schattka J H et al.Photoca-talytic properties of porous metal oxide networks formed by nanoparticle infiltration in a polymer gel template[J].Journal of Physical Chemistry B,2003,107:952.
[42] Jiu J.;Kurumada K.;Tanigaki M. .Preparation of nanoporous ZnO using copolymer gel template[J].Materials Chemistry and Physics,2003(1):93-98.
[43] Crepaldi E L et al.Controlled formation of highly ordered cubic and hexagonal mesoporous nanocrystalline yttria-zirco-nia and ceria-zirconia thin films exhibiting high thermal stability[J].Angewandte Chemie International Edition,2003,42:347.
[44] Yang P D;Zhao D Y;Stucky G D et al.Generalized syntheses of large-pore mesoporous metal oxides with semicrystal-line frameworks[J].Nature,1998,396:152.
[45] Lee B;Lu D L;Domen K.Single crystal particles of a mesoporous mixed transition metal oxide with a wormhole structure[J].Chemical Communications,2001:2118.
[46] Chao ZS.;Ruckenstein E. .Effect of the nature of the templating surfactant on the synthesis and structure of mesoporous V-Mg-O[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(3):734-743.
[47] Kang M;Kim DC;Yi S H et al.Preparation of stable mesoporous inorganic oxides via nano-replication technique[J].Catalysis Today,2004,93-95:695.
[48] Katou T;Lu D L;Kondo J N et al.Synthesis of 2D-hexago-nally ordered mesoporous niobium and tantalum mixed oxide[J].Journal of Materials Chemistry,2002,12:1480.
[49] Zou W Y;Cai Q;Cui F Z et al.Electrochemical synthesis and characterization of mesoporous Cu/Cu_2O films[J].Materials Letters,2003,57:1934.
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