综述了锂离子氧化物、硫化物玻璃及微晶玻璃固体电解质的研究进展.重点讨论了这些材料的电化学性能,以及离子掺杂对电化学性能的影响.探讨了锂离子玻璃和微晶玻璃固体电解质的发展及应用前景,认为其在全固态电池中的应用将随技术的发展实现商业化.
参考文献
[1] | Adachi G Y;Imanaka N;Aono H .Fast Li+ conducting ceramic electrolytes[J].Advanced Materials,1996,8:127. |
[2] | 郑子山,张中太,唐子龙,沈万慈.锂无机固体电解质[J].化学进展,2003(02):101-106. |
[3] | 丁飞,张晶,杨凯,刘兴江.锂离子无机固体电解质研究进展[J].电源技术,2007(06):496-499. |
[4] | Tatsumisago M .Glassy materials based on Li2S for all-solidstate lithium secondary batteries[J].Solid State Ionics,2004,175:13. |
[5] | Lee CH.;Joo KH.;Kim JH.;Woo SG.;Sohn HJ.;Kang T.;Park Y.;Oh JY. .Characterizations of a new lithium ion conducting Li2O-SeO2-B2O3 glass electrolyte[J].Solid state ionics,2002(1/2):59-65. |
[6] | 郑洪河,曲群婷,刘云伟,徐仲榆.无机固体电解质用于锂及锂离子电池研究进展--Ⅰ锂陶瓷电解质[J].电源技术,2007(05):349-353. |
[7] | 吴字平;万春荣;姜长印.锂离子二次电池[M].北京:化学工业出版社,2002 |
[8] | Komiya R.;Morimoto H.;Tatsumisago M.;Minami T.;Hayashi A. .Solid state lithium secondary batteries using an amorphous solid electrolyte in the system (100-x)(0.6Li(2)S center dot 0.4SiS(2)) center dot xLi(4)SiO(4) obtained by mechanochemical synthesis[J].Solid state ionics,2001(1/2):83-87. |
[9] | Jozwiak P;Garbarczyk JE .Mixed electronic-ionic conductivity in the glasses of the Li2O-V2O5-P2O5 system[J].Solid state ionics,2005(25/28):2163-2166. |
[10] | 许晓雄,温兆银.锂离子电池玻璃及玻璃陶瓷固体电解质材料研究[J].无机材料学报,2005(01):21-26. |
[11] | 李文,王淼,李振华,尚学府,王恒,王幼文,徐亚伯.Li2O-TiO2-SiO2-P2O5和Li2O-TiO2-Al2O3-P2O5体系锂离子固体电解质的制备及性能研究[J].无机化学学报,2006(12):2217-2221. |
[12] | Karthikeyan A;Vinatier P;Lovasseur A .Study of lithium glassy solid electrolyte/electrode interface by impedance analysis[J].Bulletin of Materials Science,2000,23:179. |
[13] | 韩德刚;高盘良.物理化学[M].北京:高等教育出版社,2001 |
[14] | 赵胜利,文九巴,顾永军,陈海云,秦启宗.玻璃态硫化物快锂离子导体研究进展[J].化学世界,2005(11):693-695,700. |
[15] | Wu Xianming et al.Synthesis of Li1.3Al0.3Ti1.7(PO4) by sol-gel technique[J].Materials Letters,2004,58:1227. |
[16] | Leo CJ.;Rao GVS.;Chowdari BVR. .Effect of MgO addition on the ionic conductivity of LiGe2(PO4)(3) ceramics[J].Solid state ionics,2003(3/4):357-367. |
[17] | 郑洪河,曲群婷,刘云伟,徐仲榆.无机固体电解质用于锂及锂离子电池研究进展--Ⅰ锂陶瓷电解质[J].电源技术,2007(05):349-353. |
[18] | Hayashi A et al.Rechargeable lithium batteries,using sulfurbased cathode materials and Li2S-P2S5 glass ceramic electrolytes[J].Electrochimica Acta,2004,50:893. |
[19] | Tachea M;Malugani J P et al.Study of the CuI-Cu2S system conductivity of the solid solution Cu1+xI1-xSx(x《0.5)[J].Solid State Ionics,1984,14:181. |
[20] | Hayashi A;Hama S;Mizuno F et al.Characterization of Li2S-P2S5 glass-ceramics as a solid electrolyte for lithium secondary batteries[J].Solid State Ionics,2004,175:683. |
[21] | Tatsumisago M.;Hama S.;Hayashi A.;Morimoto H.;Minami T. .New lithium ion conducting glass-ceramics prepared from mechanochemical Li2S-P2S5 glasses[J].Solid state ionics,2002(Pt.B):635-640. |
[22] | Ohtomo T;Mizumo F;Hayashi A et al.Electrical and electrochemical properties of Li2S-P2S5-P2O5 glass-ceramic electrolytes[J].Journal of Power Sources,2005,146:715. |
[23] | Akitoshi H;Takamasa O;Fuminori M et al.Preparation of Li2S-P2S5 amorphous solid electrolytes by mechanical mil-ling[J].Electrochemistry Communications,2003,5:70. |
[24] | Joo KH.;Vinatier P.;Pecquenard B.;Levasseur A.;Sohn HJ. .Thin film lithium ion conducting LiBSO solid electrolyte[J].Solid state ionics,2003(1/2):51-59. |
[25] | Baba M;Kumagai N;Fujita N et al.Fabrication and electrochemical characteristics of all-solid-state lithium-ion rechargeable batteries composed of LiMn2O4 positive and V2O5negative electrodes[J].Journal of Power Sources,2001,97:798. |
[26] | Takada K.;Inada T.;Kajiyama A.;Sasaki H.;Kondo S.;Watanabe M. Murayama M.;Kanno R. .Solid-state lithium battery with graphite anode[J].Solid state ionics,2003(3/4):269-274. |
[27] | Hayashi A et al.All-solid-state lithium secondary batteries with SnS-P2S5 negative electrodes and Li2S-P2S5 solid electrolytes[J].Journal of Power Sources,2005,146:496. |
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