利用微层共挤出技术对聚丙烯(PP)/乙烯-乙烯醇共聚物(EVOH)共混物进行二次加工,制备出了气体阻隔性能显著提高的PP/EVOH共混符合材料.通过电子扫描显微镜、气体渗透实验研究了微层共挤出共混物的形态结构及其对共混物阻隔性能的影响.研究结果表明,微层共挤出技术能够有效调节EVOH分散相在PP基体中的形态结构,随着层敦的增加,使其从零维球形变形为一维纤维状,进而演变成二维片状,这些形态导致128层微层共挤出共混物的气体阻隔性能较普通共混物提高了52倍.
参考文献
[1] | Demarquette NR.;Kamal MR. .Influence of maleation of polypropylene on the interfacial properties between polypropylene and ethylene-vinyl alcohol copolymer[J].Journal of Applied Polymer Science,1998(1):75-87. |
[2] | 沈佳斌,王明,李姜,杜芹,许双喜,陈光顺,郭少云.丙烯-乙烯共聚物/乙烯-1-辛烯共聚物层状复合材料的力学性能研究[J].高分子学报,2007(09):827-832. |
[3] | Xu SX;Wen M;Li J;Guo SY;Wang M;Du Q;Shen JB;Zhang YQ;Jiang SL .Structure and properties of electrically conducting composites consisting of alternating layers of pure polypropylene and polypropylene with a carbon black filler[J].Polymer: The International Journal for the Science and Technology of Polymers,2008(22):4861-4870. |
[4] | Jarus D.;Hiltner A.;Baer E. .Barrier properties of polypropylene/polyamide blends produced by microlayer coextrusion[J].Polymer: The International Journal for the Science and Technology of Polymers,2002(8):2401-2408. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%