阳极催化剂是低温燃料电池的关键材料之一,研制新型催化剂对燃料电池的性能及成本起着关键作用.从改变催化剂的组成、分散度及调控催化剂的表面结构3个方面综述了近年来低温燃料电池阳极催化剂的研究进展,并展望了该领域今后的发展方向.
The anode catalyst is one of the key materials for low temperature fuel cells, the research and development of novel catalysts play an important role for the performance and cost of fuel cells. Recent progress in the anode catalysts for low temperature fuel cells is reviewed from three aspects,which are changing the composition, dispersion and surface structure of the catalysts, and the developing directions of the anode catalysts are discussed.
参考文献
[1] | 翁端,冉锐,吴晓东.稀土催化材料的应用进展[J].稀土信息,2004(02):6-9. |
[2] | 沈培康,田植群.低温燃料电池催化剂及制备技术进展[J].世界科技研究与发展,2004(05):18-26. |
[3] | Bashyam R;Zelenay P .A class of non-precious metal composite catalysts for fuel cells[J].Nature,2006,443:63. |
[4] | Antolini E .Catalysts for direct ethanol fuel cells[J].Journal of Power Sources,2007,170:1. |
[5] | Zhou W J;Li W Z;Song S Q et al.Bi-and tri-metallic Pt-based anode catalysts for direct ethanol fuel cells[J].Journal of Power Sources,2004,131:217. |
[6] | Wang ZB;Zuo PJ;Wang GJ;Du CY;Yin GP .Effect of Ni on PtRu/C catalyst performance for ethanol electrooxidation in acidic medium[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(16):6582-6587. |
[7] | Wang Z B;Yin G P;Lin Y G .Synthesis and characterization of PtRuMo/C nanoparticle electrocatalyst for direct ethanol fuel cell[J].Journal of Power Sources,2007,170:242. |
[8] | Camara G A;de Lima R B;Iwasita T .Catalysis of ethanol electrooxidation by PtRu:The influence of catalyst composition[J].Electrochemistry Communications,2004,6:812. |
[9] | Tsiakaras P E .PtM/C(M=Sn,Ru,Pd,W) based anode direct ethanol-PEMFCs:Structural characteristics and cell performance[J].Journal of Power Sources,2007,171:107. |
[10] | Chen Y et al.Room temperature preparation of carbon supported Pt-Ru catalysts[J].Journal of Power Sources,2006,161:470. |
[11] | Lamy C;Lima A;LeRhun V et al.Recent advances in the development of direct alcohol fuel cells(DAFC)[J].Journal of Power Sources,2002,105(02):283. |
[12] | Huanqiao Li;Gongquan Sun;Lei Cao;Luhua Jiang;Qin Xin .Comparison of different promotion effect of PtRu/C and PtSn/C electrocatalysts for ethanol electro-oxidation[J].Electrochimica Acta,2007(24):6622-6629. |
[13] | 李文震,孙公权,严玉山,辛勤.低温燃料电池担载型贵金属催化剂[J].化学进展,2005(05):761-772. |
[14] | Park K W et al.Chemical and electronic effects of Ni in Pt/Ni and Pt/Ru/Ni alloy nanoparticles in methanol electrooxidation[J].Journal of Physical Chemistry B,2002,106:1869. |
[15] | Liu ZL;Hong L;Tay SW .Preparation and characterization of carbon-supported Pt, PtSnO2 and PtRu nanoparticles for direct methanol fuel cells[J].Materials Chemistry and Physics,2007(2/3):222-228. |
[16] | Guo J W;Zhao T S;Prabhuram J et al.Development of PtRu-CeO_2/C anode electrocatalyst for direct methanol fuel cells[J].Journal of Power Sources,2006,156:345. |
[17] | Wang J S;Xi J Y;Bai Y X et al.Structural designing of Pt-CeO_2/CNTs for methanol electro-oxidation[J].Journal of Power Sources,2007,164:555. |
[18] | Scibioh M A;Kim S K;Cho E A et al.Pt-CeO_2/C anode catalyst for direct methanol fuel cells[J].Applied Catalysis B:Environmental,2008,84:773. |
[19] | Bai YX;Wu JJ;Xi JY;Wang JS;Zhu WT;Chen LQ;Qiu XP .Electrochemical oxidation of ethanol on Pt-ZrO2/C catalyst[J].Electrochemistry communications,2005(11):1087-1090. |
[20] | Xu CW;Shen PK;Ji XH;Zeng R;Liu YL .Enhanced activity for ethanol electro oxidation on Pt-MgO/C catalysts[J].Electrochemistry communications,2005(12):1305-1308. |
[21] | Profeti L P R et al.Application of Pt+RuO_2 catalysts prepared by thermal decomposition of po-lymeric precursors to DMFC[J].Journal of Power Sources,2006,158:1195. |
[22] | Park KW;Sung YE;Toney MF .Structural effect of PtRu-WO3 alloy nanostructures on methanol electrooxidation[J].Electrochemistry communications,2006(2):359-363. |
[23] | Yu X W;Pickup P G .Recent advances in direct formic acid fuel cells(DFAFC)[J].Journal of Power Sources,2008,182:124. |
[24] | Wang X;Tang Y W;Gap Y et al.Carbon-supported Pd-Ir catalyst as anodic catalyst in direct formic acid fuel cell[J].Journal of Power Sources,2008,175:784. |
[25] | Wang H;Xu CW;Cheng FL;Jiang SP .Pd nanowire arrays as electrocatalysts for ethanol electrooxidation[J].Electrochemistry communications,2007(5):1212-1216. |
[26] | Xu CW;Hu YH;Rong JH;Jiang SP;Liu YL .Ni hollow spheres as catalysts for methanol and ethanol electrooxidation[J].Electrochemistry communications,2007(8):2009-2012. |
[27] | Cao L;Sun GQ;Li HQ;Xin Q .Carbon-supported IrSn catalysts for a direct ethanol fuel cell[J].Electrochemistry communications,2007(10):2541-2546. |
[28] | Guo D J;Li H L .Highly dispersed Ag nanoparticles on functional MWNT surfaces for methanol oxidation in alkaline solution[J].Carbon,2005,43:1259. |
[29] | 李金峰,宋焕巧,邱新平.直接甲醇燃料电池阳极催化剂的研究进展[J].电源技术,2007(02):167-170. |
[30] | Liu H S et al.A review of anode catalysis in the direct methanol fuel cell[J].Journal of Power Sources,2006,155:95. |
[31] | Zhiming Cui;Changpeng Liu;Jianhui Liao;Wei Xing .Highly active PtRu catalysts supported on carbon nanotubes prepared by modified impregnation method for methanol electro-oxidation[J].Electrochimica Acta,2008(27):7807-7811. |
[32] | J.Prabhuram;T.S.Zhao;Z.K.Tang;R.Chen;Z.X.Liang .Multiwalled Carbon Nanotube Supported PtRu for the Anode of Direct Methanol Fuel Cells[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2006(11):5245-5252. |
[33] | Shijun Liao;Kerry-Anne Holmes;Haralampos Tsaprailis;Viola I.Birss .High Performance PtRuIr Catalysts Supported on Carbon Nanotubes for the Anodic Oxidation of Methanol[J].Journal of the American Chemical Society,2006(11):3504-3505. |
[34] | Liu Y C;Qiu X P;Huang Y Q et al.Methanol electro-oxidation on mesocarbon microbead supported Pt catalysts[J].Carbon,2002,40:2375. |
[35] | Jin Wu;Fengping Hu;Xiduo Hu;Zidong Wei;Pei Kang Shen .Improved kinetics of methanol oxidation on Pt/hollow carbon sphere catalysts[J].Electrochimica Acta,2008(28):8341-8345. |
[36] | Zhao GW;He JP;Zhang CX;Zhou JH;Chen X;Wang T .Highly dispersed Pt nanoparticles on mesoporous carbon nanofibers prepared by two templates[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(4):1028-1033. |
[37] | J. Guo;G. San;Q. Wang .Carbon nanofibers supported Pt-Ru electrocatalysts for direct methanol fuel cells[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(1):152-157. |
[38] | K. Vinodgopal;Mehul Haria;Dan Meisel;Prashant Kamat .Fullerene-Based Carbon Nanostructures for Methanol Oxidation[J].Nano letters,2004(3):415-418. |
[39] | Kim S;Park SJ .Electroactivity of Pt-Ru/polyaniline composite catalyst-electrodes prepared by electrochemical deposition methods[J].Solid state ionics,2008(37/38):1915-1921. |
[40] | Hongbin Zhao;Lei Li;Jun Yang;Yongming Zhang .Nanostructured Polypyrrole/carbon Composite As Pt Catalyst Support For Fuel Cell Applications[J].Journal of Power Sources,2008(2):375-380. |
[41] | Zhao HB;Li L;Yang J;Zhang YM;Li H .Synthesis and characterization of bimetallic Pt-Fe/polypyrrole-carbon catalyst as DMFC anode catalyst[J].Electrochemistry communications,2008(6):876-879. |
[42] | Selvaraj V;Alagar M .Ethylene glycol oxidation on Pt and Pt-Ru nanoparticle decorated polythiophene/multiwalled carbon nanotube composites for fuel cell applications[J].Nanotechnology,2008(4):45504-1-45504-8-0. |
[43] | Vasquez, Y;Henkes, AE;Bauer, JC;Schaak, RE .Nanocrystal conversion chemistry: A unified and materials-general strategy for the template-based synthesis of nanocrystalline solids[J].Journal of Solid State Chemistry,2008(7):1509-1523. |
[44] | Xun Wang;Jing Zhuang;Qing Peng;Yadong Li .A general strategy for nanocrystal synthesis[J].Nature,2005(7055):121-124. |
[45] | Ding KL;Miao ZJ;Liu ZM;Zhang ZF;Han BX;An GM;Miao SD;Xie Y .Facile synthesis of high quality TiO2 nanocrystals in ionic liquid via a microwave-assisted process[J].Journal of the American Chemical Society,2007(20):6362-6363. |
[46] | Du D;Ding JW;Tao Y;Li HB;Chen X .CdTe nanocrystal-based electrochemical biosensor for the recognition of neutravidin by anodic stripping voltammetry at electrodeposited bismuth film[J].Biosensors & Bioelectronics: The International Journal for the Professional Involved with Research, Technology and Applications of Biosensers and Related Devices,2008(4):863-868. |
[47] | 孙世刚;樊友军.固体表面物理化学若干研究前沿[M].厦门:厦门大学出版社,2006:175. |
[48] | Fan Y J;Zhou Z Y et al.Kinetics of dissociative adsorption of ethylene glycol on Pt(100) electrode surface in sulfuric acid solutions[J].Electrochimica Acta,2004,49:4659. |
[49] | Tian N;Zhou ZY;Sun SG;Ding Y;Wang ZL .Synthesis of tetrahexahedral platinum nanocrystals with high-index facets and high electro-oxidation activity[J].Science,2007(5825):732-735. |
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