结合当前国内外关于固体氧化物燃料电池电解质10Sc1CeSZ合成技术的研究现状,提出了一种新颖的合成方法,即固液复合法(SLM),这种方法具有低成本和环境友好的特点,表现出良好的应用潜力.主要考察了氧化锆比表面积对粉体晶体结构的影响,并探讨了该方法的主要合成机理.结果表明,氧化锆比表面积大于60m2/g时可以获得纯的立方相粉体.与传统的共沉淀合成法相比,SLM法合成的粉体具有更好的微结构和烧结性能、电解质性能.烧结后的电解质片的电导率在10Sc1CeSZ电解质中处于较高水平,在800℃时达到了0.14S/cm.
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