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固相反应法合成了新型锂离子电池正极材料LiFePO4,组装成电池后,室温下(23℃)初始比容量为110mAh/g.以蔗糖分解在LiFePO4电池材料的颗粒间覆碳的方法制备了改性的LiFePO4,对LiFePO4进行表面覆碳改性后其电化学性能包括比容量和充放电效率两方面都得到提高.覆碳后正极材料的初始比容量在室温下达到了140mAh/g,比覆碳前增加了30mAh/g,在循环20周后比容量仍维持在125mAh/g左右;覆碳后正极材料的平均充放电效率在23℃和50℃下分别为91%和93%.

参考文献

[1] Nagaura T;Tozawa K .[J].Prog Batts Sol Cells,1990,9:209.
[2] Ohzuku T;Ueda A;Nagayama M et al.[J].Electrochimica Acta,1993,38:1159.
[3] GaoY;Dahn J R .[J].Applied Physics Letters,1995,66:2487.
[4] Zhang S S;JowTR .[J].Journal of Power Sources,2002,109:172.
[5] Takahashi M.;Tobishima S.;Takei K.;Sakurai Y. .Reaction behavior of LiFePO4 as a cathode material for rechargeable lithium batteries[J].Solid state ionics,2002(3/4):283-289.
[6] Padhi AK.;Goodenough JB.;Nanjundaswamy KS. .PHOSPHO-OLIVINES AS POSITIVE-ELECTRODE MATERIALS FOR RECHARGEABLE LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1997(4):1188-1194.
[7] Andersson AS.;Haggstrom L.;Thomas JO.;Kalska B. .Lithium extraction/insertion in LiFePO4: an X-ray diffraction and Mossbauer spectroscopy study[J].Solid state ionics,2000(1/2):41-52.
[8] Persi L;Croce F;Scrosati B .[J].Electrochemistry Communications,2002,4:92.
[9] Huang H;Yin;S C;Nazar L F .[J].Electrochemical and Solid-State Letters,2001,4(10):170.
[10] Yamada A;Chung S C;Hinokuma K .[J].Journal of the Electrochemical Society,2001,148(03):224.
[11] Prosini P P;Zane D;Pasquali M et al.[J].Electrochimica Acta,2001,46:3517.
[12] Ravet N;Chouinard Y;Magnan J F et al.[J].Journal of Power Sources,2001,97-98:503.
[13] Prosini PP.;Lisi M.;Zane D.;Pasquali M. .Determination of the chemical diffusion coefficient of lithium in LiFePO4[J].Solid state ionics,2002(1/2):45-51.
[14] Anderson A S;Thomas J O .[J].Journal of Power Sources,2001,97-98:498.
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