以Zn(Ac)2·2H2O、NaI和N2H4·H2O为原料,在未使用任何表面活性剂的简单水热反应体系中制得了ZnO纳米棒.采用X射线粉末衍射仪(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)对产物的晶体结构、形貌进行了表征分析,并对其光催化活性进行了探讨,以ZnO纳米棒为光催化剂对有机染料污染物甲基橙进行了光催化降解实验.实验结果表明,氧化锌纳米棒对甲基橙的光催化降解具有很好的催化作用,在紫外光照射120min后,对甲基橙的降解率接近完全.
参考文献
[1] | Naomi L. Stock;Julie Peller;K. Vinodgopal;Prashant V. Kamat .Combinative sonolysis and photocatalysis for textile dye degradation[J].Environmental Science & Technology: ES&T,2000(9):1747-1750. |
[2] | M.Muruganandham;M.Swaminathan .Photochemical oxidation of reactive azo dye with UV-H_2O_2 process[J].Dyes and Pigments,2004(3):269-275. |
[3] | Chen YF.;Yao TF.;Bagnall D. .ZnO as a novel photonic material for the UV region[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2000(2/3):190-198. |
[4] | Noriko Saito;Hajime Haneda;Takashi Sekiguchi;Naoki Ohashi;Isao Sakaguchi;Kunihito Koumoto .Low-Temperature Fabrication of Light-Emitting Zinc Oxide Micropatterns Using Self-Assembled Monolayers[J].Advanced Materials,2002(6):418-421. |
[5] | King DS.;Nix RM. .THERMAL STABILITY AND REDUCIBILITY OF ZNO AND CU/ZNO CATALYSTS[J].Journal of Catalysis,1996(1):76-83. |
[6] | Bagnall DM;Chen YF;Zhu Z;Yao T;Koyama S;Shen MY;Goto T .Optically pumped lasing of ZnO at room temperature[J].Applied physics letters,1997(17):2230-2232. |
[7] | A UMAR;B KARUNAGARAN;E-K SUH .Structural and optical properties of single-crystalline ZnO nanorods grown on silicon by thermal evaporation[J].Nanotechnology,2006(16):4072-4077. |
[8] | Lu CH;Qi LM;Yang JH;Tang L;Zhang DY;Ma JM .Hydrothermal growth of large-scale micropatterned arrays of ultralong ZnO nanowires and nanobelts on zinc substrate[J].Chemical communications,2006(33):3551-3553. |
[9] | Jia Long Yang;Sung Jin An;Won Il Park;Gyu-Chul Yi;Wonyong Choi .Photocatalysis Using ZnO Thin Films and Nanoneedles Grown by Metal-Organic Chemical Vapor Deposition[J].Advanced Materials,2004(18):1661-1664. |
[10] | 氧化锌空心球的制备及其光催化性能研究[J].人工晶体学报,2012(06):1722-1725. |
[11] | Park YK.;Kwak MG.;Yang H.;Ju SH.;Cho WS.;Han JI. .Time-resolved spectroscopic study of energy transfer in ZnO : EuCl3 phosphors[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1998(1):87-90. |
[12] | Cristian Lizama;Juanita Freer;Jaime Baeza;Hector D.Mansilla .Optimized photodegradation of Reactive Blue 19 on TiO_2 and ZnO suspensions[J].Catalysis Today,2002(2/4):235-246. |
[13] | N. Daneshvar;D. Salari;A. R. Khataee .Photocatalytic degradation of azo dye acid red 14 in water: investigation of the effect of operational parameters[J].Journal of Photochemistry and Photobiology. A, Chemistry,2003(1):111-116. |
[14] | Sakthivel S.;Neppolian B.;Shankar MV.;Arabindoo B.;Palanichamy M. Murugesan V. .Solar photocatalytic degradation of azo dye: comparison of photocatalytic efficiency of ZnO and TiO2[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(1):65-82. |
[15] | Yu Chen;Runzhou Yu;Qian Shi .Hydrothermal synthesis of hexagonal ZnO clusters[J].Materials Letters,2007(22):4438-4441. |
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