TiO2薄膜发展现状及APCVD制备掺氮TiO2性能研究

材料导报, 2006, 20(z1): 57-74.

TiO2薄膜发展现状及APCVD制备掺氮TiO2性能研究

王薇薇 ^1, , 郭玉 ^2, , 张溪文 ^3, , 韩高荣 ^4,

1.浙江大学硅材料国家重点实验室,杭州,310027

2.浙江大学硅材料国家重点实验室,杭州,310027

3.浙江大学硅材料国家重点实验室,杭州,310027

4.浙江大学硅材料国家重点实验室,杭州,310027

基金项目: 国家高技术研究发展计划(863计划)(2001AA320202) 国家自然科学基金(50372060)

关键词：光催化性 , 掺氮 , TiO2 , 薄膜 , APCVD

The Development of TiO2 Films and the Properties of N-doped TiO2 Films Prepared by APCVD

概述了TiO2的国内外发展现状,从原理、改性等方面详细介绍了TiO2的光催化特性,并对TiO2的制备方法进行了总结概括.用APCVD法所做的气体流量系列掺氮TiO2样品进行测试分析发现,氮已经掺入TiO2中,氮的掺杂改善了薄膜表面的亲水性能.

参考文献

[1]	Fujishima A;Honda K .Electrochemical photolysis of water at A semiconductor electrode[J].Nature,1972,23(5358):37.
[2]	Wang Rong;Kazuhito Hashimoto;Akira Fujishima.Lightinduced amphiphilic surfaces[J].NATURE,1997(338):432.
[3]	陈龙武,盛闻超,甘礼华.TiO2功能薄膜的制备及影响其光催化活性的因素[J].功能材料,2002(03):246-249.
[4]	姚晓斌,马颖,姚建年.Ag和Pd及其离子对TiO2光催化分解CH3CHO的影响[J].感光科学与光化学,1999(01):12-16.
[5]	姚晓斌,马颖,姚建年.贵金属对TiO2悬浮液光照过程中H2O2形成的促进作用[J].感光科学与光化学,1999(02):159-163.
[6]	魏建红,赵修建,余家国,袁润章.光催化自洁净玻璃的研制[J].硅酸盐学报,2001(01):93-96.
[7]	王幼平,余家国,赵修建,石柱明.溶胶－凝胶工艺制备掺铅TiO2纳米薄膜及其光催化性能的研究[J].中国环境科学,1998(03):244.
[8]	余家国,赵修建,赵青南.掺锡TiO2复合薄膜的制备和光催化性能的研究[J].复合材料学报,2001(01):79-82.
[9]	刘崎,陈晓青,杨娟玉,徐洪元.双元素掺杂对纳米二氧化钛光催化降解甲基橙的影响[J].河南化工,2004(02):8-10.
[10]	Choi W;Termin A;Hoffmann M R .The role of metal ion dopants in quantum-sized TiO2:correlation between photoreactivity and charge carrier recombination dynamics[J].Physical Chemistry,1994,98(05):13669.
[11]	尹荔松,沈辉.二氧化钛光催化研究进展及应用[J].材料导报,2000(12):23-25.
[12]	K. VINODGOPAL;PRASHANT V. KAMAT .Enhanced Rates of Photocatalytic Degradation of an Azo Dye Using SnO_2/TiO_2 Coupled Semiconductor Thin Films[J].Environmental Science & Technology: ES&T,1995(3):841-845.
[13]	刘平,周廷云,林华香,傅贤智.TiO2/SnO2复合光催化剂的耦合效应[J].物理化学学报,2001(03):265-269.
[14]	施利毅;古宏晨;李春忠.SnO2-TiO2复合光催化剂的制备和性能[A].,1998:338.
[15]	李文漪,李文军,武正簧,赵君芙,孙彦平,蔡珣.TiO2薄膜的光催化特性[J].上海交通大学学报,2002(01):1-4.
[16]	黄琮;王良焱;朱春媚.TiO2光催化有机污染物的研究现状与展望[J].化学通报（印刷版）,2001
[17]	Kenji Harada;Teruaki Hisanaga;Keiichi Tanaka .Photocatalytic degradation of organophosphorous insecticides in aqueous semiconductor suspensions[J].Water Research,1990,24(11):1415.
[18]	Sato S .Photocatalytic activity of NOx-doped TiO2 in the visible light region[J].Chemical Physics Letters,1986,123(1-2):126.
[19]	Asahi R;Morikawa T;Ohwakl T et al.Visible-light photocatalysis in nitrogen-doped titanium oxides[J].Science,2001,293:269.
[20]	Morikawa Takeshi;Asahi R;Ohwaki T et al.Band-gap narrowing of titanium dioxide by nitrogen doping[J].Japanese Journal of Applied Physics,2001,40(6A):L561.
[21]	Shanmuga Sakthivel;Horst Kisch .Photocatalytic and photoelectrochemical properties of nitrogen-doped titanium dioxide[J].ChemPhysChem:A European Journal of Chemical Physics and Physical Chemistry,2003,4:487.
[22]	Hiroshi Irie;Seitaro Washizuka;Norio Yoshino;Kazuhito Hashimoto .Visible-light induced hydrophilicity on nitrogen-substituted titanium dioxide films[J].Chemical communications,2003(11):1298-1299.
[23]	Clemens Burda;Yongbing Lou;Xiaobo Chen;Anna C. S. Samia;John Stout;James L. Gole .Enhanced Nitrogen Doping in TiO_2 Nanoparticles[J].Nano letters,2003(8):1049-1051.
[24]	Oliver Diwald;Tracy L. Thompson;Ed G. Goralski;Scott D. Walck;John T. Yates Jr. .The Effect of Nitrogen Ion Implantation on the Photoactivity of TiO_2 Rutile Single Crystals[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2004(1):52-57.
[25]	Shu Yin;Qiwu Zhang;Fumio Saito;Tsugio Sato .Preparation of visible light-activated titania photocatalyst by mechanochemical method[J].Chemistry Letters,2003(4):358-359.
[26]	Minero C.;Maurino V.;Vione D.;Pelizzetti E.;Mariella G. .Photocatalytic transformation of organic compounds in the presence of inorganic ions. 2. Competitive reactions of phenol and alcohols an a titanium dioxide-fluoride system[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(23):8964-8972.
[27]	Yu JC.;Yu JU.;Ho WK.;Jiang ZT.;Zhang LH. .Effects of F- doping on the photocatalytic activity and microstructures of nanocrystalline TiO2 powders[J].Chemistry of Materials,2002(9):3808-3816.
[28]	Hattori A.;Tada H.;Ito S.;Yamamoto M. .A promoting effect of NH4F addition on the photocatalytic activity of sol-gel TiO2 films[J].Chemistry Letters,1998(8):707-708.
[29]	Li Di;Hajime Haneda;Shuichi Hishita et al.Fluorinedoped TiO2 powders prepared by spray pyrolysis and their improved photocatalytic activity[J].Fluorine Chemistry,2005,126:69.
[30]	Irie H;Watanabe Y;Hashimoto K .Nitrogen-concentration dependence on photoctalytic activity of TiO2-xNx powders[J].Physical Chemistry B,2003,107:5483.
[31]	Sakthivel S;Kisch Horst .Daylight photocatalysis by carbon-modified titanium dioxide[J].Angewandte Chemie International Edition,2003,42:4908.
[32]	Tsutomu Umebayashi;Tetsuya Yamaki;Sigeru Tanaka;Keisuke Asai .Visible light-induced degradation of methylene blue on S-doped TiO_2[J].Chemistry Letters,2003(4):330-331.
[33]	T. Umebayashi;T. Yamaki;H. Itoh;K. Asai .Band gap narrowing of titanium dioxide by sulfur doping[J].Applied physics letters,2002(3):454-456.
[34]	付贤智,李旦振.提高多相光催化氧化过程效率的新途径[J].福州大学学报(自然科学版),2001(06):104-114.
[35]	谷学谦,董秀芹.光催化氧化降解有机废物研究进展[J].化学工业与工程,2004(02):142-145.
[36]	López T;Gómez R;Pecci G et al.Effect of pH on the incorporation of platinum into the lattice of sol-gel titania phases[J].Materials Letters,1999,40:59.
[37]	董昊,张永熙,杨锡良.直流反应磁控溅射制备二氧化钛薄膜的光催化性研究[J].真空科学与技术学报,2000(04):252.
[38]	Takeda S.;Odaka H.;Hosono H.;Suzuki S. .Photocatalytic TiO2 thin film deposited onto glass by DC magnetron sputtering[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2001(2):338-344.
[39]	Okada M.;Yamada Y.;Jin P.;Tazawa M.;Yoshimura K. .Fabrication of multifunctional coating which combines low-e property and visible-light-responsive photocatalytic activity[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2003(1/2):217-221.
[40]	Sun R D;Nakajima A;Fujishima A et al.Photoinduced surface wettability conversion of ZnO and TiO2 thin film[J].Physical Chemistry B,2001,105:1984.
[41]	崔丽萍,张建明.用MOCVD法制备TiO2薄膜[J].太原理工大学学报,2003(02):222-225.
[42]	曹亚安;谢腾峰;张昕彤等.TiO2纳米粒子膜表面性质的研究[J].物理化学学报,1999,15(08):680.
[43]	Shane A O'Neill;Ivan P Parkin;Robin J H Clark et al.Atmospheric pressure chemical vapour deposition of thin films of Nb2O5 on glass[J].Materials Chemistry,2003,13:56.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

TiO2薄膜发展现状及APCVD制备掺氮TiO2性能研究

The Development of TiO2 Films and the Properties of N-doped TiO2 Films Prepared by APCVD

参考文献