采用低能N-离子束对氧化石墨烯进行辐照,研究离子束辐照对石墨烯表面的改性作用,通过拉曼光谱仪(Raman)、原子力显微镜(AFM)和透射电子显微镜(TEM)表征了氧化石墨烯的辐照效果.结果表明,由于辐照产生的原子碰撞和热效应,在一定的N+辐照剂量下,氧化石墨烯表面发生原子的迁移、重排,在表面产生了纳米孔和晶化现象.Raman结果显示,相对于未辐照组,辐照后的氧化石墨烯特征峰相对强度比值ID/IG明显降低,表明离子束辐照减少了氧化石墨烯表面缺陷,具有明显的改性效果.
参考文献
[1] | Novoselov K S;Geim A K .Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666. |
[2] | Chemically Derived Graphene Oxide: Towards Large-Area Thin-Film Electronics and Optoelectronics[J].Advanced Materials,2010(22):2392-2415. |
[3] | Wang X R;Ouyang Y J .Room temperature all-semiconducting sub-10-mn graphene nanoribbon field-effect transistors[J].Physical Review Letters,2008,100(20):1. |
[4] | Choi, B.G.;Park, H.;Park, T.J.;Yang, M.H.;Kim, J.S.;Jang, S.-Y.;Heo, N.S.;Lee, S.Y.;Kong, J.;Hong, W.H. .Solution chemistry of self-assembled graphene nanohybrids for high-performance flexible biosensors[J].ACS nano,2010(5):2910-2918. |
[5] | Yan Wang;Zhiqiang Shi;Yi Huang .Supercapacitor Devices Based on Graphene Materials[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(30):13103-13107. |
[6] | Guangmin Zhou;Da-Wei Wang;Feng Li .Graphene-Wrapped Fe3O4 Anode Material with Improved Reversible Capacity and Cyclic Stability for Lithium Ion Batteries[J].Chemistry of Materials: A Publication of the American Chemistry Society,2010(18):5306-5313. |
[7] | Lee, JK;Smith, KB;Hayner, CM;Kung, HH .Silicon nanoparticles-graphene paper composites for Li ion battery anodes[J].Chemical communications,2010(12):2025-2027. |
[8] | Hydrogen Adsorption Behavior Of Graphene Above Critical Temperature[J].International journal of hydrogen energy,2009(5):2329-2332. |
[9] | Lee, H;Ihm, J;Cohen, ML;Louie, SG .Calcium-Decorated Graphene-Based Nanostructures for Hydrogen Storage[J].Nano letters,2010(3):793-798. |
[10] | Naigui Shang;Pagona Papakonstantinou;Peng Wang .Platinum Integrated Graphene for Methanol Fuel Cells[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(37):15837-15841. |
[11] | All-Carbon Electronic Devices Fabricated by Directly Grown Single-Walled Carbon Nanotubes on Reduced Graphene Oxide Electrodes[J].Advanced Materials,2010(28):982,3058-3061. |
[12] | Liu, J.;Lin, Z.;Liu, T.;Yin, Z.;Zhou, X.;Chen, S.;Xie, L.;Boey, F.;Zhang, H.;Huang, W. .Multilayer stacked low-temperature-reduced graphene oxide films: Preparation, characterization, and application in polymer memory devices[J].Small,2010(14):1536-1542. |
[13] | He, Q.;Sudibya, H.G.;Yin, Z.;Wu, S.;Li, H.;Boey, F.;Huang, W.;Chen, P.;Zhang, H. .Centimeter-long and large-scale micropatterns of reduced graphene oxide films: Fabrication and sensing applications[J].ACS nano,2010(6):3201-3208. |
[14] | Zhijuan Wang;Xiaozhu Zhou;Juan Zhang .Direct Electrochemical Reduction of Single-Layer Graphene Oxide and Subsequent Functionalization with Glucose Oxidase[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2009(32):14071-14075. |
[15] | Oka Y;Nishijima M;Hiraga K;Yatsuzuka M .Effect of ion implantation layer on adhesion of DLC film by plasma-based ion implantation and deposition[J].Surface & Coatings Technology,2007(15):6647-6650. |
[16] | Qin LZ;Wu ZL;Zhang X;Liu AD;Liao B;Deng J .Modification of DLC films by Ni+ ions implantation[J].Nuclear Instruments and Methods in Physics Research, Section B. Beam Interactions with Materials and Atoms,2008(18):3939-3944. |
[17] | M. Z. Iqbal;Arun Kumar Singh;M. W. Iqbal;Sunae Seo;Jonghwa Eom .Effect of e-beam irradiation on graphene layer grown by chemical vapor deposition[J].Journal of Applied Physics,2012(8):084307-1-084307-5. |
[18] | Bell, DC;Lemme, MC;Stern, LA;RWilliams, J;Marcus, CM .Precision cutting and patterning of graphene with helium ions[J].Nanotechnology,2009(45):455301:1-455301:5. |
[19] | D. Fox;A. O'Neill;D. Zhou;M. Boese;J. N. Coleman;H. Z. Zhang .Nitrogen assisted etching of graphene layers in a scanning electron microscope[J].Applied physics letters,2011(24):243117-1-243117-3. |
[20] | Liu, S.;Zhao, Q.;Xu, J.;Yan, K.;Peng, H.;Yang, F.;You, L.;Yu, D. .Fast and controllable fabrication of suspended graphene nanopore devices[J].Nanotechnology,2012(8):085301-1-085301-6. |
[21] | Hummers W S;Offerman R E .Preparation of graphitic oxide[J].Journal of the American Chemical Society,1958,80(06):1339. |
[22] | Zhang Y Y;Chen L et al.Preparing graphene with no etched edges and nanopore defects by γ-ray etching of graphite oxide[J].Materials Letters,2012,89:226. |
[23] | Chen J T;Zhang G G .Surface amorphization and deoxygenation of graphene oxide paper by Ti ion implantation[J].Carbon,2011,49(09):3141. |
[24] | Rossi F .Amorphisation and growth mechanisms of carbon films under ion beam irradiation[J].Chaos,Solitons and Fractals,1999,10(12):2019. |
[25] | B.S. Archanjo;I.O. Maciel;E.H. Martins Ferreira .Ion beam nanopatterning and micro-Raman spectroscopy analysis on HOPG for testing FIB performances[J].Ultramicroscopy,2011(8):1338-1342. |
[26] | 谭平恒.碳材料的拉曼光谱--从纳米管到金刚石[M].北京:化学工业出版社,2007 |
[27] | Reich S.;Thomsen C. .Comment on "polarized Raman study of aligned multiwalled carbon nanotubes"[J].Physical review letters,2000(16):3544-0. |
[28] | B. Prevel;J.-M. Benoit;L. Bardotti;P. Melinon;A. Ouerghi;D. Lucot;E. Bourhis;J. Gierak .Nanostructuring graphene on SiC by focused ion beam: Effect of the ion fluence[J].Applied physics letters,2011(8):083116-1-083116-3. |
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