采用十六烷基三甲氧基硅烷对亚微米氧化锌粉体进行表面有机化改性,将此改性氧化锌与PA6复合制得导热PA6塑料,并对其性能进行研究。结果表明:改性后氧化锌粉体的吸油值比改性前降低了67%;改性氧化锌粉体在PA6树脂基体中分散均匀,PA6表现出良好的熔体流动性;当添加改性氧化锌的体积分数为25%时,PA6塑料表现出良好的导热性和绝缘性,其热导率达到1.05 W/(m·K),体积电阻率为7.29×1010Ω·m。
A submicron zinc oxide powder was modified by hexadecyltrimethoxysilane, and a thermal con-ductive PA6 plastic was prepared by the modified zinc oxide and PA6, and its properties were studied. The results show that the oil absorption value of the modified zinc oxide decreases by 67% compared to the unmodified powder. The modified zinc oxide is well distributed in the PA6 matrix, and the PA6 plas-tic show good melt flowability. When the volume fraction of the modified zinc oxide is 25%, the PA6 plastic show good thermal conductive and insulating properties, with the thermal conductivity of 1.05 W/(m·K) and the volume resistivity of 7.29×1010Ω·m.
参考文献
[1] | Xu Yunsheng;Chung D D L;Mroz Cathleen .Thermally Conducting Aluminum Nitride Polymer-matrix Composites[J].Composites-Part A:Applied Science and Manufacturing,2011,32:1749-1757. |
[2] | 金钫,金荣福,蔡琼英,夏玉洁.LED与导热高分子复合材料[J].广东化工,2011(11):55-57. |
[3] | 刘汉,吴宏武.填充型导热高分子复合材料研究进展[J].塑料工业,2011(04):10-13. |
[4] | 王文进,李鸿岩,姜其斌.高导热绝缘高分子复合材料的研究进展[J].绝缘材料,2008(05):30-33. |
[5] | Yongcun Zhou;Hong Wang;Lu Wang .Fabrication and characterization of aluminum nitride polymer matrix composites with high thermal conductivity and low dielectric constant for electronic packaging[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2012(11):892-896. |
[6] | 林晓丹,曾幸荣,张金柱,张贞祥,徐迎宾.PA66导热绝缘塑料的制备与性能[J].工程塑料应用,2006(04):7-9. |
[7] | 李光吉,童奇勇,冯晖.聚丙烯/四针状氧化锌晶须/氧化镁导热绝缘复合材料的制备与性能研究[J].中国塑料,2010(06):28-35. |
[8] | 梁基照,刘冠生.颗粒填充聚合物复合材料导热系数公式的初步验证[J].塑料科技,2007(07):30-32. |
[9] | 李亚东,闫福丰,马亿珠,何晶.氮化铝对ABS复合材料导热性能的影响[J].塑料工业,2006(11):63-65. |
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