通过在玻璃纤维(GF)上接枝 1,3,5,7-四甲基-1,3,5,7-四乙烯基环四硅氧烷(D4Vi)的方法,制备了一种新的负载型铂基催化剂(GF-Pt).制备过程是: 先用甲基二氯硅烷对玻璃纤维表面进行硅烷化处理使玻璃纤维表面键合硅氢键,然后以Pt(0)-D4Vi络合物为催化剂催化D4Vi与硅氢键反应,从而在玻璃纤维表面接上D4Vi环并同时络合有铂.傅里叶变换红外光谱、场发射扫描电镜、 X射线能谱和热重分析研究结果表明, D4Vi环成功地以共价键键合于纤维表面.采用苯乙烯与甲基二乙氧基硅烷的硅氢化反应对该催化剂的催化性能进行了表征.结果表明,该催化剂能在室温下有效地催化硅氢化反应,能符合所设计的聚合物基自修复复合材料体系的特殊要求.
参考文献
| [1] | Marciniec B .[J].Coordination Chemistry Reviews,2005,249(21-22):2374. |
| [2] | Tanabe M;Ito D;Osakada K .Diplatinum complexes with bridging silyl ligands. Si-H bond activation of mu-silyl ligand leading to a new platinum complex with bridging silylene and silane ligands[J].Organometallics,2007(3):459-462. |
| [3] | Speier J L;Webster J A;Barnes G H .[J].Journal of the American Chemical Society,1957,79(04):974. |
| [4] | Drake R;Dunn R;Sherrington D C;Thomson S J .[J].Journal of Molecular Catalysis A:Chemical,2001,177(01):49. |
| [5] | Corma A;Garcia H .[J].Chemical Reviews,2002,102(10):3837. |
| [6] | Marciniec B;Maciejewski H;Duczmal W;Fiedorow R Kitynski D .[J].Applied Organometallic Chemistry,2003,17(02):127. |
| [7] | Meille V .Review on methods to deposit catalysts on structured surfaces[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(0):1-17. |
| [8] | Miao Q J;Fang Zh P;Cai G P .[J].Catalysis Communications,2003,4(12):637. |
| [9] | Corma A;Garcia H .Silica-bound homogenous catalysts as recoverable and reusable catalysts in organic synthesis[J].Advanced synthesis & catalysis,2006(12/13):1391-1412. |
| [10] | Planeix J M;Coustel N;Coq B;Brotons V Kumbhar P S Dutartre R Geneste P Bernier P Ajayan P M .[J].Journal of the American Chemical Society,1994,116(17):7935. |
| [11] | Corma A;Garcia H;Leyva A .Polyethyleneglycol as scaffold and solvent for reusable C-C coupling homogeneous Pd catalysts[J].Journal of Catalysis,2006(2):87-99. |
| [12] | Corma A;Garcia H .[J].Chemical Reviews,2003,103(11):4307. |
| [13] | 方征平;羊海棠;李瑞隽;顾嫒娟, 佟立芳.[A].北京,2005 |
| [14] | 方征平,羊海棠,徐立华,顾嫒娟,佟立芳,许忠斌.聚合物基复合材料自修复体系的构成与修复机制分析[J].航空材料学报,2006(03):335-336. |
| [15] | Dry C .[J].Computers & Structures,1996,35(03):263. |
| [16] | Dry C .[J].Chemical and Engineering News,2001,79(11):8. |
| [17] | Dry C;McMillan W .A novel method to detect crack location and volume in opaque and semi-opaque brittle materials[J].Smart Materials & Structures,1997(1):35-39. |
| [18] | Brown EN.;Sottos NR.;White SR. .Fracture testing of a self-healing polymer composite[J].Experimental Mechanics,2002(4):372-379. |
| [19] | Kessler MR;Larin GE;Bernklau N .Cure characterization and viscosity development of ring-opening metatihiesis polymerized resins[J].Journal of thermal analysis and calorimetry,2006(1):7-12. |
| [20] | Kessler M R;Sottos N R;White S R .[J].Composite A,2003,34(08):743. |
| [21] | Kessler M R;White S R .[J].Composite A,2001,32(05):683. |
| [22] | Kessler MR.;White SR. .Cure kinetics of the ring-opening metathesis polymerization of dicyclopentadiene[J].Journal of Polymer Science, Part A. Polymer Chemistry,2002(14):2373-2383. |
| [23] | White,SR;Sottos,NR;Geubelle,PH;Moore,JS;Kessler,MR;Sriram,SR;Brown,EN;Viswanathan,S .Autonomic healing of polymer composites.[J].Nature,2001(6822):794-797. |
| [24] | Rule J D;Brown E N;Sottos N R;White S R Moore J S .[J].Advanced Materials,2005,17(02):205. |
| [25] | Cho SH;Andersson HM;White SR;Sottos NR;Braun PV .Polydimethylsiloxane-based self-healing materials[J].Advanced Materials,2006(8):997-1000. |
| [26] | Zheng Ping FANG,Hai Tang YANG,Qian Jiang MIAO,Guo Ping CAI.Synthesis of Methyl-(γ-chloropropyl)dichlorosilane Catalyzed by Silica-supported Karstedt-type Catalyst[J].中国化学快报（英文版）,2006(09):1155-1158. |
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