溶剂热法制备太阳电池用NaYF4:Yb3+,  Er3+纳米上转换材料

材料研究学报, 2009, 23(2): 123-126.

溶剂热法制备太阳电池用NaYF₄:Yb³⁺, Er³⁺纳米上转换材料

刘永娟张晓丹王东丰张存善赵颖

1.1.南开大学光电子薄膜器件与技术研究所

光电信息技术科学教育部重点实验室(南开大学

天津大学)

天津 3000712.河北工业大学信息工程学院

天津 300130>

1.1.Institute of Photo-electronics Thin Film Devices and Technique of Nankai University

Key Laboratory of Photo-electronics Thin Film Devices and Technique of Tianjin

Key Laboratory of Photo-electronic Information Science and Technology (Nankai University

Tianjin University)

Tianjin 3000712.College of Information Engineering

Hebei University of Technology

Tianjin 300130>

基金项目: 国家高技术研究发展计划2007AA05Z436、国家重点基础研究发展计划2006CB202602和2006CB202603、国家自然科学基金60506003、南开大学博士启动基金J02031、科技部国际合作重点2006DFA62390和教育部新世纪人才计划NCET--05--0227资助项目.

关键词：无机非金属材料 , solvent , deionized water , ethanol , ethylenediaminetetraacetic acid (EDTA) , up-conversion

Optimized solvent-thermal preparation of NaYF₄ :Yb³⁺, Er³⁺ up-conversion nanoparticles for application in solar cells

LIU Yongjuan ZHANG Xiaodan WANG Dongfeng ZHANG Cunshan ZHAO Ying

Keywords： inorganic non-metallic materials , 溶剂 , 去离子水 , 乙醇 , 乙二胺四乙酸二钠(EDTA) , 上转换

用溶剂热法合成Yb³⁺、Er³⁺共掺的NaYF₄ 纳米上转换材料, 研究了去离子水、乙醇两种反应溶剂对材料性能的影响. 用X射线衍射光谱、扫描电镜和荧光光谱等测试手段对材料性能进行了对比分析. 结果表明: 以乙醇为溶剂并加入一定比例的EDTA, 所制备的上转换材料能发射较强的、可被太阳电池吸收的可见光.

Nanoparticles of Yb³⁺, Er³⁺-codoped sodium yttrium fluoride were prepared by solventthermal method. The properties of the prepared materials were characterized. The up-conversion luminescent properties of the NaYF₄: Yb³⁺, Er³⁺ nanoparticles were investigated. The effect of deionized water and ethanol as reaction medium on the performance of the up-conversion materials was studied. The results showed that the up-conversion nanoparticles had relatively high up-conversion effect when ethanol was used as reaction medium and simultaneously ethylenediaminetetraacetic acid (EDTA) was also added. The up-conversion phosphors emit visible light which could be well utilized by solar cells.

参考文献

[1]

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网