:采用工业原料通过铜模喷铸法制备了(Fe7.2B24Nb4)100-x Erx(x=3.0、4.0、4.5、5.0、6.0、7.0)块状非晶合金系,采用X射线衍射仪、DSC差示热量扫描仪研究了稀土元素Er对该非晶合金系热稳定性、玻璃形成能力的影响.结果表明:稀土元素Er的添加明显提高了样品的非晶形成能力,Er含量(摩尔分数)为5.0%时成功制备出直径为5 mm的(Fe72B24Nb4)95Er5块状非晶,该非晶合金具有较高的热稳定性,抗晶化能力较强,其晶化激活能分别达到382.8、539.5、680.8 kJ/mol.
参考文献
[1] | 苏亚坤 .四元Fe-B-Nb-Y(Er)块状非晶合金的制备及性能研究[D].东北大学,2009. |
[2] | V. Ponnambalam;S. Joseph Poon;Gary J. Shiflet .Fe-based bulk metallic glasses with diameter thickness larger than one centimeter[J].Journal of Materials Research,2004(5):1320-1323. |
[3] | Akihisa Inoue;Tsutomu Shibata;Tao Zhang .Effect of Additional Elements on Glass Transition Behavior and Glass Formation Tendency of Zr-Al-Cu-Ni Alloys[J].Materials Transactions, JIM,1995(12):1420-1426. |
[4] | A.Inoue .Stabilization of metallic supercooled liquid and bulk amorphous alloys[J].Acta materialia,2000(1):279-306. |
[5] | X.M. Huang;X.D. Wang;Y. He .Are there two glass transitions in Fe-M-Y-B (M=Mo, W, Nb)bulk metallic glasses?[J].Scripta materialia,2009(3):152-155. |
[6] | L. Liu;Z.F. Wu;J. Zhang .Crystallization kinetics of Zr_(55)Cu_(30)Al_(10)Ni_5 bulk amorphous alloy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2002(1/2):90-95. |
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