熔盐电脱氧中阴极孔隙率和半导体化影响因素的研究进展

材料导报, 2011, 25(3): 1-14.

熔盐电脱氧中阴极孔隙率和半导体化影响因素的研究进展

李泽全 ^1, , 王海华 ^2, , 白晨光 ^3, , 张娜 ^4, , 茹黎月 ^5,

1.重庆大学化学化工学院,重庆400030;重庆大学材料科学与工程学院,重庆400030

2.重庆大学化学化工学院,重庆400030

3.重庆大学材料科学与工程学院,重庆400030

4.重庆大学化学化工学院,重庆400030

5.重庆大学化学化工学院,重庆400030

基金项目: 国家科技部"863计划"资助项目(2003AA33X210) 中央高校基本科研业务费资助(CDJZR10 22 0003)

关键词：熔盐电脱氧 , 阴极性能 , 影响因素

Research Progress in Effect Factors of Porosity and Conductivity of the Cathode in Electro-deoxidation

简要介绍了熔盐电脱氧工艺制备金属或合金的研究情况.重点评述了掺杂、成形压力和烧结温度对阴极孔隙率以及掺杂、烧结温度和烧结气氛对阴极半导体化的影响,分析了阴极孔隙率和半导体化与电解效率的关系:增大阴极孔隙率,促进O<'2->扩散和迁移,增加阴极有效反应面积.有利于电解脱氧;增加阴极氧空位有利于增强其导电性,从而提高电解效率.展望了今后的研究方向,提出了阴极孔隙率和半导体化之间合理平衡、影响因素的优化和探讨等以提高电脱氧效率.

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材料期刊网

熔盐电脱氧中阴极孔隙率和半导体化影响因素的研究进展

Research Progress in Effect Factors of Porosity and Conductivity of the Cathode in Electro-deoxidation

参考文献