采用简单水热法制备了具有三维花状结构的斜方晶Bi2WO6光催化剂,利用XRD、SEM、BET等分析技术对催化剂的结构和形貌进行了表征.考察了反应时间、Bi2WO6加入量、染料罗丹明B初始浓度和光源对罗丹明B光催化降解效果的影响.实验结果表明,180℃下水热12h合成的Bi2WO6催化剂,在加入量为2g/L,溶液pH为6.5,并以模拟日光500W氙灯(不加滤光片)为光源,光照30min内,对浓度为10mg/L的罗丹明B去除率最高达99.6%.水热制备的花状Bi2WO6具有较高的光催化活性.
参考文献
[1] | Zou Z G;Ye J H;Sayama K et al.[J].Nature,2001,414:625-627. |
[2] | Yabunaka M J;Kijima T .[J].Chemistry of Materials,2000,12:812-814. |
[3] | Yin J;Zou Z G;Ye J H .[J].Journal of Physical Chemistry B,2003,107:61-65. |
[4] | Tang J W;Zou Z G;Ye J H .[J].CHEMISTRY OF MATERIALS,2004,16:1644-1648. |
[5] | Kim H G;Hwang D W;Lee J S .[J].Journal of the American Chemical Society,2004,126:8912-8913. |
[6] | Kohtani S;Koshiko M;Kudo A et al.[J].Applied Catalysis B:Environmental,2003,46:573-586. |
[7] | Gao F;Chen X;Yin K et al.[J].Advanced Materials,2007,19:2889-2892. |
[8] | Zhao X;Xu TG;Yao WQ;Zhang C;Zhu YF .Photoelectrocatalytic degradation of 4-chlorophenol at Bi2WO6 nanoflake film electrode under visible light irradiation[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2007(1/2):92-97. |
[9] | McDowell N A;Knight K S;Lightfoot P .[J].Chemistry-A European Journal,2006,12:1493-1496. |
[10] | Ricote J;Pardo L;Castro A et al.[J].Journal of Solid State Chemistry,2001,160:54-56. |
[11] | Fumiaki A;Kohei N;Ryu A et al.[J].Journal of Physical Chemistry C,2008,112:9320-9323. |
[12] | Fu HB;Zhang LW;Yao WQ;Zhu YF .Photocatalytic properties of nanosized Bi2WO6 catalysts synthesized via a hydrothermal process[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2006(1/2):100-110. |
[13] | Tang J W;Zou Z G;Ye J H .[J].Catalysis Letters,2004,92:53-58. |
[14] | Fu H B;Pan C S;Yao W Q et al.[J].Journal of Physical Chemistry B,2005,109:22432-22436. |
[15] | Zhang, C;Zhu, YF .Synthesis of square Bi2WO6 nanoplates as high-activity visible-light-driven photocatalysts[J].Chemistry of Materials,2005(13):3537-3545. |
[16] | Zhang S C;Zhang C;Man Y et al.[J].Journal of Solid State Chemistry,2006,179:62-69. |
[17] | Li YY;Liu JP;Huang XT;Li GY .Hydrothermal synthesis of Bi2WO6 uniform hierarchical microspheres[J].Crystal growth & design,2007(7):1350-1355. |
[18] | Li Y Y;Liu J P;Huang X T .[J].Nanoscale Research Letters,2008,3:365-371. |
[19] | XU C X;Wei X;Guo Y M et al.[J].Materials Research Bulletin,2009,44:1635-1641. |
[20] | 佟明明,邢冀川.氪灯和氙灯光谱强度分布和光谱效率测量[J].光学技术,2006(z1):188-191,195. |
[21] | Fu HB;Lin J;Zhang LW;Zhu YF .Photocatalytic activities of a novel ZnWO4 catalyst prepared by a hydrothermal process[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(0):58-67. |
[22] | Huang G L;Zhu Y F .[J].Mater Sci Engineer B,2007,139:201-208. |
[23] | Miki K;Sumpun W .[J].Materials Chemistry and Physics,2008,110:166-171. |
[24] | Zhang L S;Wang W Z;Chen Z G et al.[J].Journal of Materials Chemistry,2007,17:2526-2532. |
[25] | 李霞,刘艳.NaTaO3光催化剂的水热合成与催化性能研究[J].功能材料,2009(03):407-409,412. |
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