以Ti、B4C和Fe粉为原料,采用等离子束加热反应合成TiB2-TiC-Fe2Ti复合材料,分析了其物相、组织结构、显微硬度和断口形貌等.结果表明:反应生成物中物相主要有TiB2、TiC和Fe2Ti,同时含有少量的Fe3C.各物相以不同的形态均匀分布,TiB2呈现六边形和长条形,TiC近似球形,Fe2Ti作为粘结相存在于TiB2和TiC相之间,促进了各相之间的结合.等离子束加热具有高加热及冷却速率,降低了晶粒生长时间,有利于获得细小的组织.随着电流增加,单位时间内输入坯体热量增多,TiB2和TiC充分长大,各相之间结合更加紧密.
参考文献
[1] | Vallauri D,Atias Adrian I C,Chrysanthou A.TiC-TiB2 composites:a review of phase relationships,processing and properties[J].Journal of the European Ceramic Society,2008,28(8):1697-1713.,2008. |
[2] | 杜宝帅,邹增大,王新洪,等.激光熔覆原位自生TiB2 TiC/FeCrSiB复合涂层研究[J].应用激光,2007,27(4):269-272.Du Baoshuai,Zou Zengda,Wang Xinhong,et al.Investiga tion on in situ synthesis of TiB2 TiC/FeCrSiB composite coatings by laser cladding[J].Applied Laser,2007,27(4):269-272.,2007. |
[3] | Cha L,Lartigue Korinek S,Walls M,et al.Interface struc ture and chemistry in a novel steel-based composite Fe-TiB2 obtained by eutectic solidification[J].Acta Materialia,2012,60(18):6382-6389.,2012. |
[4] | Zou B,Huang C Z,Song J P,et al.Mechanical properties and microstructure of TiB2-TiC composite ceramic cutting tool material[J].International Journal of Refractory Metals and Hard Materials,2012,35:1-9.,2012. |
[5] | Wang X H,Zhang M,Du B S.Fabrication in situ TiB2 TiC-Al2O3 multiple ceramic particles reinforced Fe based composite coatings by gas tungsten arc welding[J].Tribolo gy Letters,2011,41(1):171-176.,2011. |
[6] | WangX B,Shun H L,Li C G,et al.The performances of TiB2 contained iron based coatings at high temperature[J].Surface and Coatings Technology,2006,201(6):2500-2504.,2006. |
[7] | Yang Y F,Wang H Y,Zhao R Y,et al.Effect of Ni content on the reaction behaviors of sef-propagating high tempera ture synthesis in the Ni-Ti-B4C system[J].International Journal of Refractory Metals and Hard Materials,2008,26(2):77-83.,2008. |
[8] | Zou B L,Shen P,Jing Q C.Dependence of the SHS reaction behavior and product on B4C particle size in Al-Ti-B4C and Al-TiO2-B4C systems[J].Materials Research Bulletin,2009,44(3):499-504.,2009. |
[9] | Guedea J,Yee-Madeira H,Cabanas J G.Mechanically in duced instability in Fe2Ti and mechanical alloying of Fe and Ti[J].Journal of Materials Science,2004,39 (7):2523-2528.,2004. |
[10] | Zhang X H,Yu M H,Tang H Q,etal.Effect of copper ad dition on microstructures and mechanical properties of in situ TiCp/Fe composites[J].Materials & Design,2011,32(6):3560-3565.,2011. |
[11] | 王宏亮,杨屹,冯可芹,林慧敏,王文娟.电场诱导Fe-Ti-C系燃烧合成:电流对合成产物的影响[J].稀有金属材料与工程,2007(08):1483-1486. |
[12] | Akhtar F,Hasan F.Reactive sintering and properties of TiB2 and TiC porous cermets[J].Materials Letters,2008,62(8-9):1242-1245.,2008. |
[13] | 王业亮,傅正义,王皓,张金咏.TiB2-TiC复相陶瓷的结构与性能研究[J].复合材料学报,2003(01):22-26. |
[14] | Li B H,Liu Y,Li J,et al.Effect of sintering process on the microstructures and properties of in situ TiB2-TiC reinforced steel matrix composites produced by spark plasma sintering[J].Journal of Materials Processing Technology,2010,210(1):91-95.,2010. |
[15] | Li J L,Li F,Hu K,et al.TiB2/TiC nanocomposite powder fabricated via high energy ball milling[J].Journal of the Eu ropean Ceramic Society,2001,21(16):2829-2833.,2001. |
[16] | Li W J,Tu R,Goto T.Preparation of directionally solidified TiB2 TiC eutectic composites by a floating zone method[J].Materials Letter,2006,60(6):839-843.,2006. |
[17] | 梁连杰,陈少平,刘泽锋,等.电场辅助原位合成TiB2 TiC Ni/TiAl/Ti功能梯度材料及界面结构[J].复合材料 学报,2011,28(5):139-144.Liang Lianjie,Chen Shaoping,Liu Zefeng,et al.In situ syn thesis of TiB2-TiC-Ni/TiAl/Ti functionally graded materi als by FAPAS and structural characteristics of the interface[J].Acta Materiae Compositae Sinica,2011,28(5):139-144.,2011. |
[18] | Du B S,Zou Z D,Wang X H,et al.In situ synthesis of TiB2/Fe composite coating by laser cladding[J].Materials Letters,2008,62(4 5):689-691.,2008. |
[19] | Du B S,Patital S R,Dahotre N B.Synthesis of TiB2-TiC/Fe nano composite coating by laser surface engineering[J].Optics & Laser Technology,2013,45:647-653.,2013. |
[20] | Emamian A,Corbin S F,Khajeour A.The effect of powder composition on the morphology of in situ TiC composite coat ing deposited by laser assisted powder deposition (LAPD)[J].Applied Surface Science,2012,261:201-208.,2012. |
[21] | Vallauri D,Atias Adrian I C,Chrysanthou A.TiB2-TiC composites:a review of phase relationships,processing and properties[J].Journal of the European Ceramic Society,2008,28(8):1697-1713.,2008. |
[22] | 崔洪芝,肖成柱,孙金全,杨红光.AZ91D镁合金等离子束重熔组织与性能[J].中国有色金属学报,2012(04):1000-1005. |
[23] | Vladkova T G,Keranov I L,Dineff P D,et al.Plasma based Ar+ beam assisted poly (dimethylsiloxane) surface modifica tion[J].Nuclear Instruments and Methods in Physics Re search Section B:Beam Interactions with Materials and At oms,2005,236(1-4):552-562.,2005. |
[24] | Wang Z T,Zhou X H,Zhao G G.Microstructure and forma tion mechanism of in-situ TiB2-TiC/Fe composite coating[J].Transactions of Nonferrous Metals Society of China,2008,18(4):831-835.,2008. |
[25] | Goncharuk D A,Baglyuk G A.Interaction between Fe Ti B4C powder charge components during heating[J].Powder Metallurgy and Metal Ceramics,2013,51(9 10):547-553.,2013. |
[26] | Li B H,Liu Y,Cao H,et al.Rapid synthesis of TiB2/Fe composite in situ by spark plasma sintering[J].Journal of Materials Science,2009,44(14):3909-3912.,2009. |
[27] | Nie J F,Wu Y Y,Li P T,et al.Morphological evolution of TiC form octahedron to cube induced by elemental nickel[J].CrystEngComm,2012,14(6):2213-2221.,2012. |
[28] | 廖先杰,翟玉春,谢宏伟,等.700℃熔盐电解制备固态钛铁 合金化合物[J].材料研究学报,2009,23(2):133-137.Liao Xianjie,Zhai Yuchun,Xie Hongwei,et al.Preparation of solid state Fe-Ti alloy compound by FFC in molten salts at 700 ℃[J].Chinese Journal of Materials Research,2009,23(2):133-137.,2009. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%