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以硅橡胶(MVQ)为基相,以团状模塑料为增强相,以丁苯橡胶(SBR)为相容剂制备了DMC/SBR/MVQ绝缘复合材料,研究了SBR的用量对MVQ性能的影响及混合方式和硫化条件对复合材料性能的影响。结果表明:通过SBR和MVQ共混制得的并用胶性能优于纯MVQ和DMC/MVQ的性能,DMC、SBR、MVQ最佳配比为60∶25∶75;其最佳的混炼方式是将MVQ和SBR分别进行混炼,白炭黑和DMC分批加入;最佳硫化条件为:温度180℃,压力1.2 MPa,时间15 min,制备的复合材料的体积电阻率大于4.9×1012Ω·m,SBR的加入提高了DMC/MVQ绝缘复合材料的性能。

A DMC/SBR/MVQ insulating composite was prepared using methyl vinyl silicone rubber (MVQ) as matrix, dough molding compound(DMC) as reinforced phase and butadiene-styrene rubber (SBR) as compatilizer. The effect of SBR content on the properties of the MVQ and the effects of mixed mode and vulcanization condition on the properties of the composite were studied. The results show that the properties of the MVQ and SBR blend are better than that of pure MVQ and DMC/MVQ. The best ratio of DMC, SBR and MVQ is 60∶25∶75, and the best mixed mode is that MVQ and SBR are mixed respectively, carbon-white and DMC are added in batches. The best vulcanization condition is 180 ℃ of temperature, 1.2 MPa of pressure and 15min of time. The volume resistivity of the DMC/SBR/MVQ composite is above 4.9 × 1012Ω·m. The addition of SBR can improve the properties of DMC/MVQ insulating composite.

参考文献

[1] Kemaloglu, S;Ozkoc, G;Aytac, A .Properties of thermally conductive micro and nano size boron nitride reinforced silicon rubber composites[J].Thermochimica Acta: An International Journal Concerned with the Broader Aspects of Thermochemistry and Its Applications to Chemical Problems,2010(1/2):40-47.
[2] 黄艳华,孙全吉,米志安,苏正涛,刘嘉,王景鹤.侧基对硅橡胶低温性能的影响[J].特种橡胶制品,2010(04):17-19,23.
[3] 武卫莉,田磊.核电站电缆料的制备技术及研究进展[J].高分子通报,2011(11):84-89.
[4] Joneidi I A;Jadidian J;Karimpour R.Effects of Ultraviolet Radiation and Artificial Pollution on the Leakage Current of Silicon Rubber Insulators[J].Electrical Insulation Confer-ence,2011(08):304-308.
[5] Kinoshita H;Simanaka Y;Matsuura Y et al.Influence of Silicon Contamination on Tribology in Low Earth Orbit[J].Acta Astronautica,2010,66(09):1320-1324.
[6] 张凯,吴菊英,黄渝鸿,梅军.碳黑/硅橡胶复合材料压阻性能稳定性改进研究[J].绝缘材料,2012(05):30-32.
[7] Yin S;Ma L;Wu L Z .Carbon Fiber Composite Lattice Structure Filled with Silicon Rubber[J].Procedia Engineering,2011,10:3191-3194.
[8] Wei-li Wu .Dough-Moulding Compound Reinforced Methyl Vinyl Silicone Rubber with Silica Filler[J].Polymers & Polymer Composites,2011(8):677-680.
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