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以杂氮硅三环衍生物为增粘剂,制备了加成型粘接有机硅灌封胶。研究了导热填料用量、导热填料处理方式、增粘剂用量以及A值(硅氢基与硅乙烯基摩尔比)对加成型有机硅灌封胶粘接性能影响。结果表明,当导热填料硅微粉用量150份、导热填料硅微粉采用A171表面处理、增粘剂用量2.0份、A值1.4时,制备出对铝材、PA、ABS、PC粘接性能良好且导热、阻燃等综合性能优异的加成型有机硅灌封胶。

An addition curable silicone encapsulant with the adhesion properties has been prepared with carbasi-latrane derivative as tackifier. Effects of amounts of fillers,different modification methods,amounts of the tackifier and A value on the adhesion properties of silicone encapsulants were investigated. The results showed that,when the loading quartz powder was 150 phr,modified by A171,the loading tackifier was 2 phr and A value was 1. 4,the addition curable silicone encapsulants was prepared with excellent adhesion for aluminum, PA, ABS and PC, and with excellent comprehensive properties such as thermal conductivity,flame retardance.

参考文献

[1] 郑友明;胡孝勇.大功率LED封装用加成型液体硅橡胶的研究进展[J].中国胶粘剂,2013(10):55-59.
[2] 戚云霞;赵士贵;姜伟峰;陈国文.加成型室温硫化硅橡胶的研究进展[J].有机硅材料,2006(1):34-37.
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