用DSC、XRD、SEM、FTIR和显微硬度计研究了Ge23Se67Sb10红外玻璃组织、硬度和红外透过率随热处理温度和时间的变化规律.结果发现,Ge23Se67Sb10红外玻璃的微晶化主要受热处理温度的影响,只有当热处理温度超过310℃后,才可用XRD和SEM检测出析晶峰和析晶相.微晶Ge23Se67Sb10玻璃的力学和光学性能与热处理温度和时间有关,温度低于310℃时,微晶Ge23Se67Sb10玻璃的硬度随热处理温度的升高和热处理时间的延长而缓慢增大,而其红外透过率随热处理温度和时间的变化很小;温度达到310℃后,其硬度和红外透过率随热处理温度的升高和热处理时间的延长而急剧减小.在310℃热处理70 h后,微晶Ge23Se67Sb10玻璃的显微硬度比原样提高了20%、透过率在2~12 μm波长区域内仍高达50%.
参考文献
[1] | Varshneya Arun K;Mauro Daniel J .[J].Journal of Non-Crystalline Solids,2007,353:1291. |
[2] | Harris Daniel C .[J].Infrared Physics & Technology,1998,39:185. |
[3] | Sanghera J S;Aggarwal I D;Busse L E et al.[J].PROCEEDINGS OF THE SPIE,1995,2396:71. |
[4] | Nie Jiaxiang;Xia Fang;Yu Runsheng et al.[J].Measurement,2011,44(01):298. |
[5] | Seddon A B .[J].Journal of Non-Crystalline Solids,1995,184:44. |
[6] | Zhang XH.;Guimond Y.;Bellec Y. .Production of complex chalcogenide glass optics by molding for thermal imaging[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2003(0):519-523. |
[7] | Zakery A.;Elliott SR. .Optical properties and applications of chalcogenide glasses: a review [Review][J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2003(1/3):1-12. |
[8] | Sanghera J S;Aggarwal I D .[J].Journal of Non-Crystalline Solids,1999,256-257(1-3):6. |
[9] | Terutoshi Kanamori;Yukio Terunuma;Shiro Takahashi et al.[J].Journal of Lightwave Technology,1984,2(05):607. |
[10] | Zhang XH.;Ma HL.;Lucas J.;Guimond Y.;Kodjikian S. .Optical fibers and molded optics in infrared transparent glass-ceramic[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2004(1):49-52. |
[11] | Sanghera Jas S;Brandon Shaw L;Aggarwal Ishwar D.[J].IEEE Journal of Quantum Electronics,2009(15):114. |
[12] | Chen Guorong;Cheng Jijian .[J].Journal of the American Ceramic Society,1998,71(06):1695. |
[13] | Zhu Shizhen;Ma Hongli;Calvez L et al.[J].Journal of Non-Crystalline Solids,2007,353:1298. |
[14] | Aly K A;Osman M A;Abousehly A M et al.[J].Journal of Non-Crystalline Solids,2008,69:2514. |
[15] | Zhang X H;Calvez L;Seznec V et al.[J].Journal of Non-Crystalline Solids,2006,352:2415. |
[16] | Calvez L;Ma HL;Lucas J;Zhang XH .Glasses and glass-ceramics based on GeSe2-Sb2Se3 and halides for far infrared transmission[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2008(12/13):1123-1127. |
[17] | Kerker M.The Scattering of Light and Other Electromagnetic Radiation[M].New York:Academic Press,Inc,1969:666. |
[18] | Li Yuanqing;Fu Shaoyun;Yang Yang et al.[J].Chemistry of Materials,2008,20(08):2637. |
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