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研究了MgO-Al2O3-Re2O3(Re=Lu,Y)三元烧结助剂体系对无压烧结Si3N4陶瓷显微结构和力学性能的影响.研究结果表明,添加MgO-Al2O3-Lu2O3三元助剂制备的Si3N4陶瓷显微结构具有明显的双峰分布,晶粒较粗化,致密度、硬度、弯曲强度、断裂韧性分别为96.4%、14.59 GPa、964 MPa、7.64 MPa·m1/2;而添加MgO-Al2O3-Y2O3三元助剂制备的Si3N4陶瓷具有细化的显微结构,致密度、硬度、弯曲强度、断裂韧性分别为99.9%、15.29 GPa、758 MPa、6.60 MPa·m1/2.

参考文献

[1] Sampad K. Biswas;Frank L. Riley.Gas Pressure Sintering of Silicon Nitride Powder Coated with Al_2O_3 and TiO_2[J].Journal of the American Ceramic Society,20032(2):212-216.
[2] Gayle S. Painter;Paul F. Becher.Bond Energetics at Intergranular Interfaces in Alumina-Doped Silicon Nitride[J].Journal of the American Ceramic Society,20021(1):65-67.
[3] Hai-Doo Kim;Byung-Dong Han;Dong-Soo Park.Novel Two-Step Sintering Process to Obtain a Bimodal Microstructure in Silicon Nitride[J].Journal of the American Ceramic Society,20021(1):245-252.
[4] Angel De Pablos;Joaquin Bermudo;Maria Isabel Osendi.Microstructure and Mechnical Properties of Silicon Nitride Materials Fabricated from SHS Powders[J].Journal of the American Ceramic Society,20015(5):1033-1036.
[5] Yang J-F.;Ohji T..Influence of Yttria-Alumina Content on Sintering Behavior and Microstructure of Silicon Nitride Ceramics[J].Journal of the American Ceramic Society,20008(8):2094-2096.
[6] Ling Gao;Haitao Yang;Runzhang Yuan.Sintering and microstructure of silicon nitride with magnesia and cerium additives[J].Journal of Materials Processing Technology,20013(3):298-301.
[7] Paul F. Becher;Gayle S. Painter;Naoya Shibata.Effects of Rare-Earth (RE) Intergranular Adsorption on the Phase Transformation, Microstructure Evolution, and Mechanical Properties in Silicon Nitride with RE_2O_3+MgO Additives: RE = La, Gd, and Lu[J].Journal of the American Ceramic Society,20087(7):2328-2336.
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