A nanocomposite of nickel oxide/carbon nanotubes was prepared through a simple chemical precipitation followed by thermal annealing. The electrochemical capacitance of this electrode material was studied. When the mass fraction of CNTs (carbon nanotubes) in NiO/CNT composites increases, the electrical resistivity of nanocomposites decreases and becomes similar to that of pure CNTs when it reaches 30%. The specific surface area of composites increases with increasing CNT mass fraction and the specific capacitance reaches 160 F/g under 10 mA/g discharge current density at CNT mass fraction of 10%.
参考文献
[1] | B E Conway.Electrochemical Supercapacitors: Scientific Fundamentals and Technological Applications, Klumer Academic/Plenum Publishers[M].New York,1999:3-18. |
[2] | B E Conway .[J].Journal of the Electrochemical Society,1991,138:1539. |
[3] | S Sarangapani;B V Tilak;C P Chen .[J].Journal of the Electrochemical Society,1996,143:3791. |
[4] | D.Qu;H.Shi .[J].Journal of Power Sources,1998,74:99. |
[5] | E.Frackowiak;F.Beguin .[J].Carbon,2001,39:937. |
[6] | R. Kotz;M. Carlen .Principles and applications of electrochemical capacitors[J].Electrochimica Acta,2000(15/16):2483-2498. |
[7] | C.G.Z.Chen;M.S.P. Shaffer;D.Coleby;G.Dixon, W.Zhou, D.J.Fray A.H.Windle [7]C.G.Z.Chen, M.S.P. Shaffer, D.Coleby, G.Dixon, W.Zhou, D.J.Fray A.H.Windle .[J].Advanced Materials,2000,12:522. |
[8] | K H An;K K Jeon;J K Heo;S.C.Lim, D.J.Bae Y.H.Lee .[J].Journal of the Electrochemical Society,2002,149:A1058. |
[9] | M.Hughes;G.Z.Chen;M.S.P.Shaffer;D.Coleby, D.J.Fray A.H.Windle .[J].Chemistry of Materials,2002,14:1610. |
[10] | M.Hughes;M.S.P. Shaffer;A.C.Renouf;C.Singh, G.Z.Chen, D.J.Fray A.H.Windle .[J].Advanced Materials,2002,14:382. |
[11] | J P Zheng;T R Jow .[J].Journal of the Electrochemical Society,1995,142:L6. |
[12] | J P Zheng;P J Cygan;T R Jow .[J].Journal of the Electrochemical Society,1995,142:2699. |
[13] | K C Liu;M A Anderson .[J].Journal of the Electrochemical Society,1996,143:124. |
[14] | V Srinivasan;J W Weidner .[J].Journal of the Electrochemical Society,1997,144:L210. |
[15] | V Srinivasan;J W Weidner .[J].Journal of the Electrochemical Society,2000,147:880. |
[16] | K W Nam;K B Kim .[J].Journal of the Electrochemical Society,2002,149:A346. |
[17] | K.W.Nam;W.S.Yoon;K.B.Kim .[J].Electrochimica Acta,2002,47:3201. |
[18] | C Lin;J A Ritter;B N Popov .[J].Journal of the Electrochemical Society,1998,145:4097. |
[19] | V.Srinivasan;J.W.Weidner .[J].Journal of Power Sources,2002,108:15. |
[20] | H Y Lee;J B Goodenough .[J].Journal of Solid State Chemistry,1999,144:220. |
[21] | H.Y.Lee;S.W.Kim;H.Y.Lee .[J].Electrochemical and Solid-State Letters,2001,4:A19. |
[22] | J.Jiang;A.Kucernak .[J].Electrochimica Acta,2002,47:2381. |
[23] | H Kim;B N Popov .[J].Journal of the Electrochemical Society,2003,150:D56. |
[24] | Niu E K Sichel;R Hoch;D Moy;H. Tennent .[J].Applied Physics Letters,1997,70:1480. |
[25] | R.Z. Ma;J. Liang;B.Q. Wei .Study of electfochemical capacitors utilizing carbon nanotube electrodes[J].Journal of Power Sources,1999(1):126-129. |
[26] | K.H.An;W.S.Kim;Y.S.Park;Y.C.Choi, S.M.Lee, D.C.Chung, D.J.Bae, S.C.Lim Y.H.Lee .[J].Advanced Materials,2001,13:497. |
[27] | 梁逵,陈艾,冯哲圣,叶芝祥.碳纳米管电极超大容量离子电容器交流阻抗特性[J].物理化学学报,2002(04):381-384. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%