采用微波水热法,分别以氯化锰和硫代乙酰胺为锰源和硫源,在不同的pH条件下合成了γ-MnS微晶.利用X射线衍射仪(XRD),扫描电子显微镜(SEM),场发射扫描电子显微镜(FESEM),透射电子显微镜(TEM)对样品的物相组成和微观形貌,粒径大小进行了表征.结果表明:在pH大于6时均能合成出结晶性较好的纤锌矿结构γ-MnS,随着pH的增大,产量提高,产物的粒径逐渐变小且自组装为球状微晶,粒径为0.5μm,利用紫外-可见吸收光谱分析(UV),自组装γ-MnS微晶球在300 ～400 nm处出现了较强的吸收峰,其光学带隙随着pH的增大而减小,在光电领域具有潜在的应用.
参考文献
| [1] | Kis J;Tang K B;Yang Q;et el.Sulvothermal Synthesis of Metostable γ-MnS Hollow Spheres and Control of Their Phase[J].European Journal of lnorganic Chemistry,2005:4124-4128. |
| [2] | Amirav L;Lifshitz E .Spray-produced Coral-shapod Assemblies of MnS Nanocrystal Clusters[J].Journal of Physical Chemistry B,2006,110(42):20922-20926. |
| [3] | Zhang YC.;Wang H.;Wang B.;Yan H.;Yoshimura M. .Low-temperature hydrothermal synthesis of pure metastable gamma-manganese sulfide (MnS) crystallites[J].Journal of Crystal Growth,2002(1):214-217. |
| [4] | Jun Lu;Pengfei Qi;Yiya Peng;Zhaoyu Meng;Zhiping Yang;Weichao Yu;Yitai Qian .Metastable MnS Crystallites through Solvothermal Synthesis[J].Chemistry of Materials,2001(6):2169-2172. |
| [5] | Fan DB.;Wang H.;Zhang YC.;Cheng H.;Wang B.;Yan H. .Preparation of crystalline MnS thin films by chemical bath deposition[J].Materials Chemistry and Physics,2003(1):44-47. |
| [6] | Jianping Ge;Yadong Li .Controllable CVD route to CoS and MnS single-crystal nanowires[J].Chemical communications,2003(19):2498-2499. |
| [7] | C. D. Lokhande;A. Ennaoui;P. S. Patil;M. Giersig;M. Muller;K. Diesner;H. Tributsch .Process and characterisation of chemical bath deposited manganese sulphide(MnS) thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1998(2):70-75. |
| [8] | Okajima M;Tohda J .Heteroepitaxial Growth of MnS On GaAs Substrates[J].Journal of Crystal Growth,1992,117(1-4):810-815. |
| [9] | Wang SB;Li KW;Zhai R;Wang H;Hou YD;Yan H .Synthesis of metastable gamma-manganese sulfide crystallites by microwave irradiation[J].Materials Chemistry and Physics,2005(2/3):298-300. |
| [10] | Zhang YC.;Wang H.;Wang B.;Yan H.;Yoshimura M. .Low-temperature hydrothermal synthesis of pure metastable gamma-manganese sulfide (MnS) crystallites[J].Journal of Crystal Growth,2002(1):214-217. |
| [11] | Hang X H;Chen Y Q;Jia C et al.Two-step Sulvothermal Synthesis of α-MnS Spheres:Growth Mechanism and Characterization[J].Materials Letters,2008,62:125-127. |
| [12] | 胡宝云,黄剑锋,张钦峰,张海,曹丽云,吴建鹏.模板剂对微波水热合成CdS微晶相组成、形貌及光学性能的影响[J].人工晶体学报,2011(01):139-143. |
| [13] | Shi Y;Xue F H;Li C Y et al.Preparation and Hydrothermal Annealing of Pure Metastable β-MnS Thin Films by Chemical Bath Deposition (CBD)[J].Materials Research Bulletin,2011,46:483-486. |
| [14] | 柴多里,杨少东,袁新松,杨保俊.α-MnS纳米晶的制备与表征[J].硅酸盐学报,2011(07):1175-1178. |
| [15] | Jianfeng Huang;Changkui Xia;Liyun Cao .Facile microwave hydrothermal synthesis of zinc oxide one-dimensional nanostructure with three-dimensional morphology[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2008(3):187-193. |
| [16] | 齐慧,黄剑锋,曹丽云,李嘉胤,吴建鹏.微波水热时间对CuS微晶形貌及光学性能的影响[J].人工晶体学报,2011(05):1188-1193. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%