采用机械共混法制备了复合材料Bi2Te3/PAn,并对其电化学嵌锂性能进行了研究.研究发现Bi2Te3/PAn快速充放电性能良好,在以100 mA·g-1的电流密度充放电时首次可逆容量为480 mAh·g-1,到第20个循环时容量保持在200mAh·g-1.通过非原位X射线衍射方法研究其嵌锂机理,发现Bi2Te3在首次放电时分解,在随后的循环中以Te和Bi为嵌锂中心进行可逆储锂.
参考文献
[1] | Tatsumi K.;Sakaebe H.;Shioyama H.;Higuchi S.;Mabuchi A. Fujimoto H.;Iwashita N. .THE INFLUENCE OF THE GRAPHITIC STRUCTURE ON THE ELECTROCHEMICAL CHARACTERISTICS FOR THE ANODE OF SECONDARY LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1995(3):716-720. |
[2] | Xing W;Xu J S;Zheng T .Correlation between Lithium Intercalation Capacity and Microstructure in Hard Carbon[J].Journal of the Electrochemical Society,1996,143(07):2137. |
[3] | Scrosati B .A High-Rate Carbon Electrode for Rechargeable Lithium-ion Batteries[J].Journal of Power Sources,1996,143(03):L64. |
[4] | Zheng T.;Fuller EW.;Tseng S.;Vonsacken U.;Dahn JR.;Liu YH. .LITHIUM INSERTION IN HIGH CAPACITY CARBONACEOUS MATERIALS[J].Journal of the Electrochemical Society,1995(8):2581-2590. |
[5] | Kenji Sato;Minoru Noguchi et al.A Mechanism of Lithium Storage in Disordered Carbons[J].Science,1994,264(04):556. |
[6] | Brousse T;Retoux R;Schleich D M .Thin-Film Crystalline SnO2-Lithium Electrodes[J].Journal of the Electrochemical Society,1998,145(01):1. |
[7] | Courtney IA.;Dahn JR. .KEY FACTORS CONTROLLING THE REVERSIBILITY OF THE REACTION OF LITHIUM WITH SNO2 AND SN2BPO6 GLASS[J].Journal of the Electrochemical Society,1997(9):2943-2948. |
[8] | Wang Y.;Huang C.;Surampudi S.;Greenbaum SG.;Sakamoto J. .Lithium-7 NMR investigation of electrochemical reaction of lithium with SnO[J].Solid state ionics,1998(3/4):167-172. |
[9] | Nagayama M.;Ikuta H.;Wakihara M.;Takano M.;Kawasaki S.;Morita T. .A new anode material SnSO4 for lithium secondary battery[J].Solid state ionics,1998(1/2):33-38. |
[10] | Idota Y;Kubota T;Matsufuji A .Tin-Based Amorphous Oxides:A High Capacity Ion-Storage Material[J].Science,1997,276(07):1395. |
[11] | YANG J;Takeda Y;Imanishi N et al.Ultrafine Sn and SnSb0.44 Powders for Lithium Storage Matrices in Lithium Ion Batteries[J].Journal of the Electrochemical Society,1999,146:4009. |
[12] | Wang G X;Sun L;Bradhurst D H et al.Lithium Storage Prosperities of Nanocrystalline Eta-Cu6Sn5 Alloys Prepared by Ball-Milling[J].Journal of Alloys and Compounds,2000,299:L12. |
[13] | Mao Ou;Dunlap R A;Dahn J R .Mechanically Alloyed Sn-Fe(-C-) Powders as Anode Materials for Li-ion Batteries -The Sn2Fe System[J].Journal of the Electrochemical Society,1999,146:405. |
[14] | Ou Mao;J. R. Dahn .Mechanically alloyed Sn-Fe(-C) powders as anode materials for Li-ion batteries: II. the Sn-Fe system[J].Journal of the Electrochemical Society,1999(2):414-422. |
[15] | Ou Mao;J. R. Dahn .Mechanically alloyed Sn-Fe(-C) powders as anode materials for Li-ion batteries: III. Sn{sub}2Fe:SnFe{sub}3C active/inactive composites[J].Journal of the Electrochemical Society,1999(2):423-427. |
[16] | Hansu Kim;Byungwoo Park;Hun-Joon Sohn et al.Electrochemical Characteristics of Mg-Ni Alloys as Anode Materials for Secondary Li Batteries[J].Journal of Power Sources,2000,90:59. |
[17] | Hirojki Sakaguchi;Hitohiko Honda;Takao Esaka .Synthesis and Anode Behavior Lithium Storage Intermetallic Compounds with Various Crystallinities[J].Journal of Power Sources,1999,81~82:229. |
[18] | Yim W M;Rosi F D .Compound Tellurides and Their Alloys for Peltier Cooling - A Review[J].Solid-State Electronics,1972,15:1121. |
[19] | DRABBLE J R;Goodman C H L .Chemical Bonding in Bismuth Telluride[J].Journal of Physics and Chemistry of Solids,1958,5(01):142. |
[20] | Robert A Huggins .Lithium Alloy Negative Electrodes Formed from Convertible Oxides[J].Solid State Ionics,1998,113~115:57. |
[21] | Fauteux D;Koksbang R .Rechargeable Lithium Battery Anodes:Alternatives to Metallic Lithium[J].Journal of Applied Electrochemistry,1993,23:1. |
[22] | Gospodinova N.;Terlemezyan L. .Conducting polymers prepared by oxidative polymerization: Polyaniline [Review][J].Progress in Polymer Science,1998(8):1443-1484. |
[23] | Morales GM.;Miras MC.;Barbero C.;Llusa M. .EFFECTS OF HIGH HYDROCHLORIC ACID CONCENTRATION ON ANILINE CHEMICAL POLYMERIZATION[J].Polymer: The International Journal for the Science and Technology of Polymers,1997(20):5247-5250. |
[24] | 胡淑红,赵新兵,朱铁军,周邦昌.Bi0.5Sb1.5Te3/聚苯胺复合材料的制备及电学性能[J].材料研究学报,2001(02):260-262. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%