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在分析锂离子电池正极材料研究进展的基础上,开展了Li2FeSiO4的合成与改性研究,采用湿化学法-高温固相合成法制备了Li2FeSiO4/C正极材料.系统研究了回流过程和煅烧温度对Li2FeSiO4/C正极材料的影响.结果表明,采用回流、煅烧温度为650℃的样品首次放电容量为165mAh/g,经过10次循环后为138mAh/g,循环性能较好.

参考文献

[1] Anton Nytén;M(a)rten Stjerndahl et al.Surface characterization and stability phenomena in Li2FeSiO4 studied by PES/XPS[J].Journal of Materials Chemistry,2006,16:3483.
[2] Anton Nytén;Saeed Kamali;Lennart H(a)ggstro(o)m et al.The lithium extraction/insertion mechanism in Li2FeSiO4[J].Journal of Materials Chemistry,2006,16:2266.
[3] Zaghib K;AitSalah A;Ravet N et al.Structural,magnetic and electrochemical properties of lithium iron orthosilicate[J].Journal of Power Sources,2006,160:1381.
[4] Nyten A;Abouimrane A;Armand M;Gustafsson T;Thomas JO .Electrochemical performance of Li2FeSiO4 as a new Li-battery cathode material[J].Electrochemistry communications,2005(2):156-160.
[5] Dominko R;Bele M;Gaberscek M;Meden A;Remskar M;Jamnik J .Structure and electrochemical performance of Li2MnSiO4 and Li2FeSiO4 as potential Li-battery cathode materials[J].Electrochemistry communications,2006(2):217-222.
[6] R. Dominko;D.E. Conte;D. Hanzel;M. Gaberscek;J. Jamnik .Impact of synthesis conditions on the structure and performance of Li_2FeSiO_4[J].Journal of Power Sources,2008(2):842-847.
[7] Dominko R .Li2MSiO4(M=Fe and Mn)cathode materials[J].Journal of Power Sources,2008,184:462.
[8] Gong Z L et al.Systhesis and characterization of Li2Mnx-Fe1-x SiO4 as a cathode material for lithium-ion batteries[J].Electrochemical and Solid State Letters,2006,9(12):A542.
[9] Gong, ZL;Li, YX;He, GN;Li, J;Yang, Y .Nanostructured Li2FeSiO4 electrode material synthesized through hydrothermal-assisted sol-gel process[J].Electrochemical and solid-state letters,2008(5):A60-A63.
[10] 杨勇;李益孝;龚正良 .可充电锂电池用硅酸锰铁锂碳复合材料及其制备方法[P].CN,1803608,2006.
[11] 彭忠东,曹雁冰,胡国荣,杜柯,蒋庆来.锂离子电池正极材料Li2FeSiO4/C的微波合成[J].中国有色金属学报,2009(08):1449-1454.
[12] Arroyo-de Dompablo ME;Armand M;Tarascon JM;Amador U .On-demand design of polyoxianionic cathode materials based on electronegativity correlations: An exploration of the Li2MSiO4 system (M = Fe, Mn, Co, Ni)[J].Electrochemistry communications,2006(8):1292-1298.
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