离子液体具有宽的电化学窗口、优良的导电性、高的热稳定性、可回收等优点,在绿色冶金电化学方面具有很大的应用潜力和广阔的应用前景.本文介绍了离子液体在活泼金属沉积中应用的研究现状,重点对锂、钠、镁等活泼金属在离子液体中的电化学行为及电沉积进行了阐述,提出了离子液体在金属电沉积应用中存在的一些问题及解决办法,并展望了未来的发展趋势.
参考文献
[1] | 李汝雄.绿色溶剂--离子液体的合成与应用[M].北京:化学工业出版社,2004:10-16. |
[2] | John D. Stenger-Smith;Cynthia K. Webber;Nicole Anderson .Poly(3,4-alkylenedioxythiophene)-Based Supercapacitors Using Ionic Liquids as Supporting Electrolytes[J].Journal of the Electrochemical Society,2002(8):A973-A977. |
[3] | V. S. Fung;D. R. Zhu .Electrodeposited Tin Coating as Negative Electrode Material for Lithium-Ion Battery in Room Temperature Molten Salt[J].Journal of the Electrochemical Society,2002(3):A319-A324. |
[4] | KUBO W;MURAKOSHI K;KITAMURA T et al.Quasi-solid-state dyesensitized TiO2 solar cells:Effective charge transport in mesoporous space filled with gel electrolytes containing iodide and iodine[J].Journal of Physical Chemistry B,2001,105(51):12809-12815. |
[5] | SCORDILIS-KELLEY C;FULLER J;CARLIN R T .Alkali metal reduction potentials measured in chloroaluminate ambient-temperature molten salts[J].Journal of the Electrochemical Society,1992,139(03):694-699. |
[6] | Gray GE.;Winnick J.;Kohl PA. .STABILITY OF SODIUM ELECTRODEPOSITED FROM A ROOM TEMPERATURE CHLOROALUMINATE MOLTEN SALT[J].Journal of the Electrochemical Society,1995(11):3636-3642. |
[7] | Gray GE.;Kohl PA.;Winnick J. .PLATING END SHIPPING OF SODIUM FROM A ROOM TEMPERATURE 1,2-DIMETHYL-3-PROPYLIMIDAZOLIUM CHLORIDE MELT[J].Journal of the Electrochemical Society,1996(7):2262-2266. |
[8] | Piersma BJ.;Schumacher ER.;Riechel TL.;Ryan DM. .ELECTRODEPOSITION AND STRIPPING OF LITHIUM AND SODIUM ON INERT ELECTRODES IN ROOM TEMPERATURE CHLOROALUMINATE MOLTEN SALTS[J].Journal of the Electrochemical Society,1996(3):908-913. |
[9] | Christopher M. Lang;Ketack Kim;Paul A. Kohl .Catalytic additives for the reversible reduction of sodium in chloroaluminate ionic liquids[J].Electrochimica Acta,2006(19):3884-3889. |
[10] | Shaohua Fang;Li Yang;Jixian Wang;Huanqi Zhang;Kazuhiro Tachibana;Kouichi Kamijima .Guanidinium-based ionic liquids as new electrolytes for lithium battery[J].Journal of Power Sources,2009(2):619-622. |
[11] | Po-Yu Chen;Charles L. Hussey .Electrodeposition of cesium at mercury electrodes in the tri-1 -butylmethylammonium bis((trifluoromethyl)sulfonyl)imide[J].Electrochimica Acta,2004(28):5125-5138. |
[12] | Po-Yu Chen .Electrochemical Behavior of the Li~+/Li Couple and Stability of Lithium Deposits in Tri-1-butylmethylammonium bis((trifluoromethyl)sulfonyl)imide Room Temperature Ionic Liquid[J].Journal of the Chinese Chemical Society,2006(5):1017-1026. |
[13] | Christopher A. Paddon;Richard G. Compton .Underpotential Deposition of Lithium on Platinum Single Crystal Electrodes in Tetrahydrofuran[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(26):9016-9018. |
[14] | Tsunashima, K;Sugiya, M .Electrochemical Behavior of lithium in room-temperature phosphonium ionic liquids as lithium battery electrolytes[J].Electrochemical and solid-state letters,2008(2):A17-A19. |
[15] | L. H. S. Gasparotto;N. Borisenko;N. Bocchi .In situ STM investigation of the lithium underpotential deposition on Au(111) in the air-and water-stable ionic liquid 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide[J].Physical chemistry chemical physics: PCCP,2009(47):11140-11145. |
[16] | D.Aurbach;Y.Gofer;Z.Lu .A short review on the comparison between Li battery systems and rechargeable magnesium battery technology[J].Journal of Power Sources,2001(0):28-32. |
[17] | YAZAKI T;SHIBATA M;HORIUCHI S.Anodic behavior of Mg alloy (AZ31) in ionic liquid[A].Tokyo:The Electrochemical Society,Inc,2004:2242-2244. |
[18] | Viestfrid Y;Levi MD;Gofer Y;Aurbach D .Microelectrode studies of reversible Mg deposition in THF solutions containing complexes of alkylaluminum chlorides and dialkylmagnesium[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2005(2):183-195. |
[19] | NuLi YN;Yang J;Wu R .Reversible deposition and dissolution of magnesium from BMIMBF4 ionic liquid[J].Electrochemistry communications,2005(11):1105-1110. |
[20] | Nuli YN;Yang J;Wang P .Electrodeposition of magnesium film from BMIMBF4 ionic liquid[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(23):8086-8090. |
[21] | Feng ZZ;Nuli Y;Wang JL;Yang J .Study of key factors influencing electrochemical reversibility of magnesium deposition and dissolution[J].Journal of the Electrochemical Society,2006(10):C689-C693. |
[22] | Wang P;NuLi YN;Yang J;Feng ZZ .Mixed ionic liquids as electrolyte for reversible deposition and dissolution of magnesium[J].Surface & Coatings Technology,2006(6):3783-3787. |
[23] | 努丽燕娜,杜国栋,冯真真,沈佳妮,杨军.碳酸乙烯酯添加剂对BMImBF4离子液体作为镁沉积-溶解电解液的改性研究[J].化学学报,2008(02):175-180. |
[24] | Cheek GT;O'Grady WE;El Abedin SZ;Moustafa EM;Endres F .Studies on the electrodeposition of magnesium in ionic liquids[J].Journal of the Electrochemical Society,2008(1):D91-D95. |
[25] | 马梅彦,左勇,张海朗,蔡迎军,张锁江.离子液体中MgCl2·6H2O脱水及电沉积[J].过程工程学报,2011(02):209-214. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%