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提出利用真空室残余的低浓度N原子制备超薄α-Ta(N)/TaN双层扩散阻挡层的方法,有效地避免了异质元素的引入和高N含量导致的高电阻率.用四点探针(FPP)、X射线衍射(XRD)、场发射扫描电子显微镜(FESEM)进行薄膜电性能和微结构的表征,分析结果表明,利用低浓度氮化工艺,能调控超薄金属Ta膜的相结构,从而获得低阻α-Ta(N)/TaN双层Cu扩散阻挡层结构.高温退火的实验结果证明,此超薄结构具有高的热稳定性,失效温度达600℃.

参考文献

[1] TWGs .International Technology Roadmap for Semiconductors (ITRS)[R].Contacts,2010.
[2] Yang LY;Zhang DH;Li CY;Foo PD .Comparative study of Ta, TaN and Ta/TaN bi-layer barriers for Cu-ultra low-k porous polymer integration[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2004(0):176-181.
[3] Xie Q;Qu XP;Tan JJ;Jiang YL;Zhou M;Chen T;Ru GP .Superior thermal stability of Ta/TaN bi-layer structure for copper metallization[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2006(3):1666-1672.
[4] Zhou YM;Xie Z;Xiao HN;Hu PF;He J .Effects of deposition parameters on tantalum films deposited by direct current magnetron sputtering[J].Vacuum: Technology Applications & Ion Physics: The International Journal & Abstracting Service for Vacuum Science & Technology,2008(2):286-291.
[5] Bae JW;Lim JW;Mimura K;Isshiki M .Ion beam deposition of alpha-Ta films by nitrogen addition and improvement of diffusion barrier property[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(11):4768-4773.
[6] Stavrev M;Fischer D;Preuss A et al.Study of nanocrystalline Ta(N,O) diffusion barriers for use in Cu metallization[J].Microelectronic Engineering,1997,33(1-4):269-275.
[7] Kee-Won Kwon;Hoo-Jeong Lee;Robert Sinclair .Solid-state amorphization at tetragonal-Ta/Cu interfaces[J].Applied physics letters,1999(7):935-937.
[8] HOO-JEONG LEE;KEE-WON KWON;CHANGSUP RYUt .THERMAL STABILITY OF A Cu/Ta MULTILAYER; AN INTRIGUING INTERFACIAL REACTION[J].Acta materialia,1999(15/16):3965-3975.
[9] Rossnagel SM. .Characteristics of ultrathin Ta and TaN films[J].Journal of Vacuum Science & Technology, B. Microelectronics and Nanometer Structures: Processing, Measurement and Phenomena,2002(6):2328-2336.
[10] Saha R;Barnard J A .Effect of structure on the mechanical properties of Ta and Ta(N) thin films prepared by reactive DC magnetron sputtering[J].Journal of Crystal Growth,1996,174:495-500.
[11] Liu L.;Gong H.;Wang Y. .Annealing effects of tantalum films on Si and SiO2/Si substrates in various vacuums[J].Journal of Applied Physics,2001(1):416-420.
[12] Knepper R;Stevens B;Baker SP .Effect of oxygen on the thermomechanical behavior of tantalum thin films during the beta-alpha phase transformation[J].Journal of Applied Physics,2006(12):23508-1-23508-11-0.
[13] Yoon DS.;Kang BS.;Lee SM.;Baik HK. .EFFECT OF INTERPOSED CR LAYER ON THE THERMAL STABILITY OF CU/TA/SI STRUCTURE[J].Journal of Applied Physics,1996(11):6550-6552.
[14] Yu-Sheng Wang;Chi-Cheng Hung;Wen-Hsi Lee;Shih-Chieh Chang;Ying-Lang Wang .Under-layer behavior study of low resistance Ta/TaN_x barrier film[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(16):5241-5243.
[15] Chen GS.;Huang SC.;Lee HY.;Chen ST. .Growth mechanism of sputter deposited Ta and Ta-N thin films induced by an underlying titanium layer and varying nitrogen flow rates[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2001(0):353-357.
[16] Tsao JC;Liu CP;Wang YL;Chen KW;Lo KY .Mechanism of over-etching defects during Ta/TaN barrier resputtering in micro-trench for Cu metallization[J].The journal of physics and chemistry of solids,2008(2/3):561-565.
[17] Tsao JC;Liu CP;Wang YL;Wang YS;Chen KW .Controlling Ta phase in Ta/TaN bilayer by surface pre-treatment on TaN[J].The journal of physics and chemistry of solids,2008(2/3):501-504.
[18] Min K H;Chun K C;Kim K B .Comparative study of tantalum and tantalum nitrides (Ta2N and TaN) as a diffusion barrier for Cu metallization[J].Journal of Vacuum Science and Technology B:Microelectronics and Nanometer Structures,1996,14(05):3263-3269.
[19] G. S. Chen;S. T. Chen .Diffusion barrier properties of single- and multilayered quasi-amorphous tantalum nitride thin films against copper penetration[J].Journal of Applied Physics,2000(12):8473-8482.
[20] Wen Luh Yang;Wen-Fa Wu;Don-Gey Liu .Barrier capability of TaN_x films deposited by different nitrogen flow rate against Cu diffusion in Cu/TaN_x/n+ -p junction diodes[J].Solid-State Electronics,2001(1):149-158.
[21] Ji-cheng Zhou;You-zhen Li;Di-hui Huang .Fabrication and diffusion barrier properties of nanoscale Ta/Ta-N bi-layer[J].Journal of Materials Processing Technology,2009(2):774-778.
[22] Ying Wang;Changchun Zhu;Zhongxiao Song;Ying Li .High temperature stability of Zr-Si-N diffusion barrier in Cu/Si contact system[J].Microelectronic engineering,2004(1):69-75.
[23] Atsuko Sekiguchi;Junichi Koike;Kouichi Maruyama .Microstructural and morphological changes during thermal cycling of Cu thin films[J].日本金属学会誌,2000(5):379-382.
[24] Z. H. Cao;K. Hu;X. K. Meng .Diffusion barrier properties of amorphous and nanocrystalline Ta films for Cu interconnects[J].Journal of Applied Physics,2009(11):113513-1-113513-5.
[25] Chen G S;Huang S C;Chen S T et al.An optimal quasisuperlatticc design to further improve thermal stability of tantalum nitride diffusion barriers[J].Applied Physics Letters,2000,76(20):2895-2897.
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