Effects of Mg on the chemical component and size distribution of Tibearing inclusions favored grain refinement of the welding induced coarsegrained heat affected zone (CGHAZ), with enhanced impact toughness in Tikilled steels, which were examined based on experimental observations and thermodynamic calculations. The results indicated that the chemical constituents of the inclusions gradually varied from the TiO+TiMgO compound oxide to the TiMgO+MgO compound oxide and the singlephase MgO, as the Mg content increased from 0002 3% to 0006%. A trace addition of Mg (approximately 0002%) led to the refinement of Tibearing inclusions by creating the TiMgO compound oxide and provided favorable size distribution of the inclusions for acicular ferrite transformation with a high nucleation rate in the CGHAZ, and a high volume fraction of acicular ferrite was obtained in the CGHAZ with enhanced impact toughness. Otherwise, a high content of Mg (approximately 0006%) produced a singlephase MgO, which was impotent to nucleate an acicular ferrite, and a microstructure comprised of a ferrite side plate and a grain boundary ferrite developed in the CGHAZ. The experimental results were confirmed by thermodynamic calculations.
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