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利用钽丝作为热线的瞬态双热线系统对温度区间233-373K、压力区间为0.1—30 MPa的液相二乙二醇单甲醚(diethylene glycol monom ethylether,DGMME)的导热系数进行了实验研究,并将实验数据拟合为温度和压力的关联式。实验数据与导热系数关联式计算结果的标准偏差和最大偏差分别为0.23%和0.86%,导热系数的合成标准不确定度小于±1.0%。

The thermal conductivity of liquid diethylene glycol monomethyl ether (DEGMME) was measured from 233 to 373 K and pressures from 0.1 to 30 MPa, by the transient hot-wire technique employing two anodized tantalum hot wires. The experimental data was correlated as a function of temperature and pressure. The absolute average deviation and the maximum deviation of the experimental results from the correlated equation were 0.23% and 0.86%. The uncertainty of the thermal conductivity was 11.0% with a coverage factor of k ±2.

参考文献

[1] Li, XX;Zhou, WD;Li, XY;Sun, JL;Jiang, W .Density, viscosity, and excess properties of the binary mixture of diethylene glycol monomethyl ether plus water at T = (293.15,303.15,313.15,323.15,333.15) K under atmospheric pressure[J].Journal of Molecular Liquids,2009(2/3):73-76.
[2] Singh, T;Kumar, A .Volumetric behaviour of 1-Butyl-3-Methyl imidazolium hexafluorophosphate with ethylene glycol derivatives: Application of Prigogine-Flory-Patterson theory[J].Journal of Molecular Liquids,2010(2/3):117-123.
[3] Jiangtao Wu;Xiaojing Li;Huifeng Zheng .Thermal Conductivity of Liquid Dimethyl Ether from (233 to 373) K at Pressures up to 30MPa[J].Journal of Chemical and Engineering Data: the ACS Journal for Data,2009(6):1720-1723.
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