研究表明:在620℃煅烧后,模板除去,TiO2形成.产物主要由TiO2和少量的H2Ti3O7组成.得到的产物的比表面积为252.6m2/g.P-C-I测试结果表明,30℃时TiO2显示可逆的吸/放氢过程.在吸/放氢过程中,化学键发生微小的偏移,表明氢可能和OH基团发生反应.随着吸/放氢循环的增加以及比表面积的明显的降低,多孔/中空TiO2坍塌.同时,随着温度的升高,化学吸附量增加,吸氢量升高.
参考文献
[1] | Kang J Im;Bai S C;Suh B C et al.[J].International Journal of Hydrogen Energy,2011,36:1560. |
[2] | Be'nard P;Chahine R .[J].Scripta Materialia,2007,56:803. |
[3] | Peng B;Li LL;Ji WQ et al.[J].JAlloy Compd,2009,484(1-2):308. |
[4] | Wang L F;Yang R T .[J].JPhys Chem C,2009,113:21883. |
[5] | Zhao W;Fierro V;Zlotea C et al.[J].International Journal of Hydrogen Energy,2011,36(09):5431. |
[6] | Gogotsi Y;Portet C;Osswald S et al.[J].lnt J Hydrogen Energy,2009,34(15):6314. |
[7] | Hirscher M;Panella B .[J].JAlloy Compd,2005,404-406:399. |
[8] | Tian H Y;Buckley C E;Sheppard D A et al.[J].International Journal of Hydrogen Energy,2010,35(24):13242. |
[9] | Lu S M;Jung H;Chun H et al.[J].International Journal of Hydrogen Energy,2009,34(24):9754. |
[10] | Darkrim F L;Malbrunot P;Tartaglia G P .[J].International Journal of Hydrogen Energy,2002,27(02):193. |
[11] | Ma R;Bondso Y;Zhu H et al.[J].Journal of the American Chemical Society,2002,124:7672. |
[12] | Chen J;Li S L;Tao Z L et al.[J].Journal of the American Chemical Society,2003,125:5284. |
[13] | Pan H;Luo J Z;Sun H et al.[J].NANOTECHNOLOGY,2006,17:2963. |
[14] | Ahmad M;Din R;Pan C F et al.[J].J Phys Chem C,2010,114:2560. |
[15] | Jiang J H;Gao Q M;Zheng Z J et al.[J].International Journal of Hydrogen Energy,2010,35:210. |
[16] | Fang BZ;Kim M;Kim JH;Yu JS .Controllable Synthesis of Hierarchical Nanostructured Hollow Core/Mesopore Shell Carbon for Electrochemical Hydrogen Storage[J].Langmuir: The ACS Journal of Surfaces and Colloids,2008(20):12068-12072. |
[17] | Lim S H;Luo J;Zhong Z Y et al.[J].Inorganic Chemistry,2005,44:4124. |
[18] | Yang H G;Zeng H C .[J].Journal of the American Chemical Society,2005,127:270. |
[19] | 19 Bavykin D V;Lapkin A A;Plucinski P K et al.[J].Journal of Physical Chemistry B,2005,109:19422. |
[20] | Wang P;Wang A M;Zhang H F et al.[J].Journal of Alloys and Compounds,2000,313(1-2):218. |
[21] | Cui, JJ;He, W;Liu, HT;Liao, SJ;Yue, YZ .Ordered hierarchical mesoporous anatase TiO2 from yeast biotemplates[J].Colloids and Surfaces, B. Biointerfaces,2009(1):274-278. |
[22] | Jha Anal K;Prasad K;Kulkarni A R .[J].Colloids Surfaces B,2009,71:226. |
[23] | Bai B;Wang P;Wu L et al.[J].Materials Chemistry and Physics,2009,114:26. |
[24] | Tian, X.;He, W.;Cui, J.;Zhang, X.;Zhou, W.;Yan, S.;Sun, X.;Han, X.;Han, S.;Yue, Y. .Mesoporous zirconium phosphate from yeast biotemplate[J].Journal of Colloid and Interface Science,2010(1):344-349. |
[25] | Fan X J;Song X Q;Yang X H et al.[J].Materials Research Bulletin,2011,46:1315. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%