材料期刊网

A systematic (Gd1-xREx)5Si4 (RE=Dy, Ho) alloys are investigated to estimate their magnetocaloric effect. The Curie points of (Gd1-x REx)Si4 alloys can tunable from 266 K to 336 K when RE=Dy, Ho; x=0~0.35 and 0~0.15, respectively, and decrease nearly linearly with increasing x. These alloys keep orthorhombic structures Ge5Sm4 and exhibit second order transition when they experience in a change magnetic field at about Curie points. The weight and voluminal magnetic entropy changes are about 3.5 J/(kg•K) and 23~29 mJ/(cm3•K) when magnetic field changes 0~2 T. The adiabatic temperatures changes (▽Tad) of these alloys at Curie points are larger than 1 K in a field change 0~1.4 T, the curve of ▽Tad is wide as that of Gd. The relative cooling power is about 0.8~0.9 J/cm3 when field changes 0~2 T, 55% of that of Gd. Comparing with Gd5(Si1-xGex)4, these alloys do not contain expensive element Ge, so that their cost are lower than the former. Because they could work at temperature region 260~340 K due to their Curie points can be tuned, which is an advantage comparing with Gd, these alloys are potential magnetic refrigerants working in a magnetic refrigerator with a low magnetic field at room temperatures.