欢迎登录材料期刊网

材料期刊网

高级检索

锌电极材料的优良缓蚀剂汞有剧毒,以苯并咪唑缓蚀剂取代汞有益于环保。采用失重法、电化学方法等研究了0.1mol/LKOH溶液中苯并咪唑对锌的缓蚀性能。结果表明:苯并咪唑能有效抑制锌的阳极氧化,从而抑制锌在碱液中的自腐蚀,属于阳极型缓蚀剂;当苯并咪唑浓度为10.0mmol/L时缓蚀效果最佳,缓蚀率可达96.68%;苯并咪唑在锌表面的吸附符合Langmuir等温式,属于化学吸咐。

参考文献

[1] Visscher W;Einerhand R E;Barendrecht E et al.Zinc electrode shape change[J].Journal of the Electrochemical Society,1991,138(01):1-17.
[2] Mc Breen J .Rechargeable zinc batteries[J].Journal of Electroanal Chem and Interfacial Electrochem,1984,168:415-432.
[3] Bass K;Mitchell P J;Wilcox G D et al.Methods for the reduction of shape change and dendritic growth in zinc-based secondary cells[J].Journal of Power Sources,1991,35(03):333-351.
[4] Einerhand R E F;Visscher W .Zinc electrode shape change process and mechanism[J].Journal of the Electrochemical Society,1991,138(01):7-17.
[5] Mc Breen J;Gannon E .The electrochemistry of metal oxide additives in pasted zinc electrodes[J].Electrochimica Acta,1981,26(10):1439-1446.
[6] Mc Breen J;Gannon E .The effect of additives on current distribution in pasted zinc electrodes[J].Journal of the Electrochemical Society,1983,130(10):1980-1982.
[7] Wilcox G D;Mitchell P J .Electrolyte additives for zinc-anoded secondary cells quaternary ammonium compounds[J].Journal of Power Sources,1990,32(01):31-41.
[8] Sato Y;Kanda M;Niki H et al.Long life sealed nickel-zinc cell using a new separator[J].Journal of Power Sources,1983,9(02):147-159.
[9] Woumfo E D;Vittori O .Electrochemical behavior of a zinc electrode in 8M KOH under pulsed potential loading[J].Journal of Applied Electrochemistry,1991,21(01):77-83.
[10] 黎学明;陶长元;张胜涛 .化学镀铟集流体对锌粉析氢行为的影响[J].电池,1999,29(03):100-102.
[11] 刘天晴,邹爱华,郭荣.表面活性剂和助表面活性剂对镍的缓蚀作用[J].物理化学学报,2000(10):899-905.
[12] 叶明库.Zn在KOH水溶液中的阳极溶解和钝化机理[J].高等学校化学学报,1981(03):337-350.
[13] Bouklah M;Hammouti B;Lagrene M et al.Thermodynam-ic properties of 2,5-bis-( 42 methoxyphenyl ) 21,3,42 oxadiazole as a corrosion inhibitor for mild steel in normal sulfuric acid medium[J].Corrosion Science,2006,48:2831-2842.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%