综述了稀土(镁)系AB2型贮氢合金的研究进展,分别从合金的晶体结构、气态贮氢性能及电化学性能等方面进行了总结,阐述了AB2与AB5及A7B16结构之间的关联性,并就此合金存在的问题加以评述,进一步探讨了改善该体系合金性能的方法.稀土(镬)系AB2型贮氢合金较AB5型和AB3型具有更高的理论贮氢容量,认为通过合理的制备工艺与机理研究能获得良好的电化学性能.
参考文献
| [1] | 雷永泉;万群;石定康.新能源材料[M].天津:天津大学出版社,2000:52. |
| [2] | 张羊换,王国清,董小平,郭世海,任江远,王新林.AB2型Laves相贮氢合金的研究进展[J].金属功能材料,2005(04):25-30. |
| [3] | Kim DM;Lee J.-Y. --;Jang K.-J. -- .Review on the development of AB sub 2 -type Zr-based Laves phase hydrogen storage alloys for Ni-MH rechargeable batteries in the Korea Advanced Institute of Science and Technology[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(0):583-592. |
| [4] | 李书存,赵敏寿.钒基固溶体贮氢合金研究现状[J].稀有金属,2007(04):558-564. |
| [5] | Tsukahara M;Takahashi K;Mishima T et al.Influence of various additives in vanadium-based alloys V3TiNi0.55 on secondary phase formation,hydrogen storage properties and electrode properties[J].Journal of Alloys and Compounds,1996,245:59. |
| [6] | 韩晓英,张羊换,王新林,王国清.球磨镁基贮氢合金的研究[J].电池,2006(03):170-172. |
| [7] | Iwakura C.;Zhang SG.;Nohara S.;Inoue H. .Hydriding and electrochemical characteristics of a homogeneous amorphous Mg2Ni-Ni composite[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):142-144. |
| [8] | Kadir K;Sakai T;Uahara I .Synthesis and structure determination of a new series of hydrogen storage alloys;RMg2Ni9(R=La,Ce,Pr,Nd,Sm and Gd) built from MgNi2 Laves-type layers alternating with AB5 layers[J].Journal of Alloys and Compounds,1997,257:115. |
| [9] | Kadir K;Nuriyama N;Sakai T et al.Structural investigation and hydrogen capacity of CaMg2 Ni9:a new phases in the AB2C9 system isostructural with LaMg2Ni9[J].Journal of Alloys and Compounds,1999,284:145. |
| [10] | Kadir K;Sakai T;Uahara I .Structural investigation and hydrogen capacity of YMg2Ni9 and (Y0.5Ca0.5) (MgCa) Ni9,new phases in the AB2C9 system isostructural with LaMg2 Ni9[J].Journal of Alloys and Compounds,1999,287:264. |
| [11] | Kadir K;Sakai T;Uahara I .Structural investigation and hydrogen capacity of LaMg2Ni9 and (La0.55Ca0.35) (Mg1.32-Ca0.68)Ni9,of the AB2C9 type structure[J].Journal of Alloys and Compounds,2000,302:112. |
| [12] | Kohno T;Yoshida H;Kawashima F et al.Hydrogen storage properties of new ternary system alloys:La2MgNi9,La5Mg2Ni23.La3Mg2Ni14[J].Journal of Alloys and Compounds,2000,311:L5. |
| [13] | 刘永锋,潘洪革,高明霞,朱云峰,葛红卫,李寿权,雷永泉.稀土镁基贮氢电极合金的结构与电化学性能研究[J].金属学报,2003(06):666-672. |
| [14] | 周增林,宋月清,崔舜,林晨光,曲选辉.Nd替代La对La-Mg-Ni系A2B7型贮氢电极合金性能的影响[J].中国有色金属学报,2007(01):45-52. |
| [15] | 董小平,张羊换,冯猛,王国清,王新林.快淬La-Mg-Ni系贮氢电极合金的结构与电化学性能[J].材料导报,2005(04):124-127. |
| [16] | Kadir K;Noreus D;Yamashita I .Structure determination of AMgNi4 (Where A = Ca,La,Ce,Pr,Nd and Y) in the AuBe5 type structure[J].Journal of Alloys and Compounds,2002,345:140. |
| [17] | Wang Z M;Zou Z Y;Gu Z F.Preparation of LaMgNi4 alloy and its electrode properties[J].Journal of Alloys and Compounds,2004(377):L7. |
| [18] | Matsuura M;Kim S H;Sakurai M et al.Local structure of the pseudo-binary Ce(Ni1-xFex)2 alloys exhibiting anomalous lattice parameter change[J].Physica B,1995,208-209:283. |
| [19] | Thoma D J;Perepezko J H .A geometric analysis of solubility ranges in Laves phases[J].Journal of Alloys and Compounds,1995,224:330. |
| [20] | Klimyenko A V;Seuntjens J;Miller L L et al.Structure of LaNi2.286 and the La-Ni system from LaNi1.75 to LaNi2.50[J].Journal of the Less-Common Metals,1988,144:133. |
| [21] | Wang Y B;Northwood D O .Calculation of enthalpy of metal hydride formation and prediction of hydrogen site occupancy[J].Journal of Materials Science and Technology,1988,4:97. |
| [22] | Magee C B;Liu J;Lundin C E .Relationship between intermetallic compound structure and hydride formation[J].Journal of the Less-Common Metals,1981,78:119. |
| [23] | Ivey D G;Northwood D O .Storing hydrogen in AB2 Lavestype compounds[J].Zeitschrift für Physikalische Chemie,1986,147:191. |
| [24] | Lichty L;Shinar J;Barnes R G et al.Composition-dependent hydrogen motion in a random alloy,VxNb1-xH0.2:From localized motion at V atoms to long-range hydrogen diffusion[J].Physical Review Letters,1985,55:2895. |
| [25] | Shoemaker D P;Shoemaker C B .Concerning atomic sites and capacities for hydrogen absorption in the AB2 Friauf-Laves phases[J].Journal of the Less-Common Metals,1979,68:43. |
| [26] | Jacob I;Shaltiel D .Hydrogen sorption properties of some AB2 Laves phase compounds[J].Journal of the Less-Common Metals,1979,65:117. |
| [27] | Didisheim J J;Yvon K .The deuterium site occupation in ZrV2Dx as a function of the deuterium concentration[J].Journal of the Less-Common Metals,1980,73:355. |
| [28] | Dunlap B D;Vicearo P J;Shenoy G K .Structural relationships in rare earth-transition metal hydrides[J].Journal of the Less-Common Metals,1980,74:75. |
| [29] | Liang Jin;Ma Xianfeng;Tang Jinkui et al.Formation and structure of LaNi2 intermetallic compound under high pressure[J].Intermetallics,2003,11:875. |
| [30] | Guenee L;Favre-Nicolin V;Yvon K et al.Synthesis,crystal structure and hydrogenation properties of the ternary compounds LaNi4 Mg and NdNi4 Mg[J].Journal of Alloys and Compounds,2003,348:129. |
| [31] | Oesterreieher H;Bittner H .Hydride formation in La1-x-MgxNi2[J].Journal of the Less-Common Metals,1980,73:339. |
| [32] | Oesterreicher H;Clinton J;Bittner H .Hydrides of La-Ni compounds[J].Materials Research Bulletin,1976,11:1241. |
| [33] | Buschow K H J .Note on the magnetic properties of Y-Mn compounds and their hydrides[J].Solid State Communications,1977,21:1031. |
| [34] | Jacob I;Shaltiel D .Hydrogen absorption in Zr(AlxB1-x) (B=Fe,Co) Laves phase compounds[J].Solid State Communications,1978,27:175. |
| [35] | Shaltiel D .Hydride properties of AB2 Laves phase compounds[J].Journal of the Less-Common Metals,1978,62:407. |
| [36] | Aoki K;Yamamoto T;Masumoto T et al.Hydrogen induced amorphization in RNi2 laves phases[J].Scripta Metallurgica et Materialia,1987,21:27. |
| [37] | Miyamura H;Sakai T;Oguro A et al.Hydrogen absorption and phase transitions in rapidly quenched La-Ni alloys[J].Journal of the Less-Common Metals,1989,146:197. |
| [38] | 罗永春,章应,阎汝煦,张法亮,康龙,陈剑虹.La2-xMgNi9-5x （x=0～1.0）贮氢合金的晶体结构与电化学性能研究[J].中国稀土学报,2005(01):11-15. |
| [39] | Miyamura H;Kuriyama N;Sakai T et al.Characteristics of electrodes using amorphous AB2 hydrogen storage alloys[J].Journal of the Less-Common Metals,1991,172-174:1205. |
| [40] | Miyamura H;Kuriyama N;Sakai T et al.Hydrogen diffusion in amorphous LaNi2Hx thin films[J].Journal of Alloys and Compounds,1993,192:188. |
| [41] | 赵敏寿,刘玉萍,乔玉卿,孙长英,朱新坚.稀土基AB2型金属氢化物电极衰变机理的探索[J].功能材料,2004(z1):1905-1907. |
| [42] | Yu X J;Zhao M S;Sun C Y.LaNi2 and LaNi2.8 hydride electrode materials[A].北京:中国铁道出版社,2000:1093. |
| [43] | Liu Y P;Wu Y M;Sun C Y.Electrochemical characteristic of LaNiz-based hydrogen storage alloy[A].北京:中国铁道出版社,2000:575. |
| [44] | Chai Zhigang.Preparation of LaAl2 alloy and its electrochemicd properties[A].北京:中国铁道出版社,2000:1103. |
| [45] | 章应,罗永春,王大辉,张法亮,康家晨,闫如煦.AB2型LaMgNi3.7M0.3（M=Ni、Al、Mn、Co、Sn、Cu）贮氢合金的晶体结构及电极性能[J].功能材料,2005(09):1372-1376. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%