通过高温固相反应法合成了层状K4Nb6O17,采用X射线衍射、比表面积测定、扫描电镜等对K4Nb6O17进行了结构和形貌表征.在I-为电子给体、RuO2为助催化剂的情况下研究了RuO2的负载量、I-离子浓度和溶液pH值对K4Nb6O17光催化分解水产氢活性的影响.研究结果表明,表面负载RuO2可以显著提高K4Nb6O17光催化产氢速度.当I-浓度为15mmol/L,pH=9,RuO2负载量为0.7%时,约400nm紫外光辐射下K4Nb6O17光催化产氢的活性最佳,氢气生成的速度为798.9μmol/L·h.
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