The polycrystalline Eu2+ and Dy3+ co-doped strontium aluminates SrAl2O4: Eu2+,Dy3+ with different compositions were prepared by solid state reactions. The UV-excited photoluminescence, persistent luminescence and thermo-luminescence were studied and compared. Results show that the doped Eu2+ ion in SrAl2O4: Eu2+, Dy3+phosphors works as not only the UV-excited luminescent center but also the persistent luminescent center. The doped Dy3+ ion can hardly yield any luminescence under UV-excitation, but effectively enhance the persistent luminescence and thermo-luminescence of SrAl2O4: Eu2+. Dy3+ co-doping can help form electron traps with appropriate depth due to its suitable electro-negativity, and increase the density and depth of electron traps. Based on above observations, a persistent luminescence mechanism, electron transfer model, is proposed and illustrated.
参考文献
[1] | Peng TY;Huajun L;Yang HP;Yan CH .Synthesis of SrAl2O4 : Eu, Dy phosphor nanometer powders by sol-gel processes and its optical properties[J].Materials Chemistry and Physics,2004(1):68-72. |
[2] | Z.-X. Yuan;C.-K. Chang;D.-L. Mao .Effect of composition on the luminescent properties of Sr_4Al_(14)O_(25): Eu~(2+), Dy~(3+) phosphors[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2004(1/2):268-271. |
[3] | Yamamoto H;Matsuzawa T .Mechanism of long phosphorescence of SrAl2O4:Eu2+, Dy3+ and CaAl2O4:Eu2+, Nd3+[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1997(0):287-289. |
[4] | Matusuazawa T;Aoki Y;Takeuchi N et al.A New Long Phosphorescent Phosphor with High Brightness SrAl2O4:Eu2+,Dy3+[J].Journal of the Electrochemical Society,1996,143(08):2670-2674. |
[5] | Jia WY.;Lu LZ.;Liu HM.;Yen WM.;Yuan HB. .Phosphorescent dynamics in SrAl2O4 : Eu2+, Dy3+ single crystal fibers[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1998(0):424-428. |
[6] | Jia W;Yuan H;Hoimstrom S et al.Photo-stimulated Luminescence in SrAl2O4:Eu2+,Dy3+ Single Crystal Fibers[J].Journal of Luminescence,1999,83-84:469-465. |
[7] | Qiu J.;Tanaka K.;Shimizugawa Y.;Hirao K.;Kawasaki M. .Phenomenon and mechanism of long-lasting phosphorescence in Eu2+-doped aluminosilicate glasses[J].The journal of physics and chemistry of solids,1998(9):1521-1525. |
[8] | Aitasalo T.;Deren P.;Holsa J.;Jungner H.;Krupa JC.;Lastusaari M. Legendziewicz J.;Niittykoski J.;Strek W. .Persistent luminescence phenomena in materials doped with rare earth ions[J].International Journal of Quantum Chemistry,2003(1/2):114-122. |
[9] | Jorma Holsa;Hogne Jungner;Mika Lastusaari .Persistent luminescence of Eu~(2+) doped alkaline earth aluminates, MAl_2O_4:Eu~(2+)[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2001(0):326-330. |
[10] | Aitasaloa Tuomas;Holsa Jorma;Jungner Hogne et al.Mechanisms of Persistent Luminescence in Eu2+,RE3+ Doped Alkaline Earth Aluminates[J].Journal of Luminescence,2001,94-95:59-63. |
[11] | T Aitasalo;J Holsa;H Jungner et al.Thermoluminescence Study of Persistent Luminescence Materials:Eu2+-and R3+-doped Calcium Aluminates,CaAl2O4:Eu2+,R3+[J].Journal of Physical Chemistry B,2006,110(10):4589-4598. |
[12] | 吕兴栋,舒万艮,黄可龙.SrO/Al2O3比率对Sr2AlO4:Eu,Dy发光性能的影响[J].发光学报,2004(06):673-678. |
[13] | Abbruscato V .Optical and Delectrical Properties of SrAl2O4:Eu2+[J].Journal of Electrochemical Society:Solid State Science,1971,118(06):930-933. |
[14] | Lin Yuanhua;Tang Zilong;Zhang Zhongtai et al.Influence of Co-doping Different Rare Rarth Ions on the Luminescence of CaAl2O4-based Phosphors[J].Journal of the European Ceramic Society,2003,23(02):175-178. |
[15] | R. Sakai;T. Katsumata;S. Komouro;T. Morikawa .Effect of composition on the phosphorescence from BaAl_2O_4: Eu~(2+), Dy~(3+) crystals[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,1999(1/3):149-154. |
[16] | McKeever S W S.Thermoluminescence of Solid[M].London:cambridge University Press,1985 |
[17] | Kim T K;Woo J J;Choe H S et al.Thermoluminescence from Ultraviolet Exposed MgAl2O4[J].Radiation Protection Dosimetry,1999,84(03):297-302. |
[18] | Su Qiang.Rare Earth Chemistry[M].郑州:河南科学技术出版社,1993 |
[19] | Abanti Nag;T.R.N. Kutty .Role of B_2O_3 on the phase stability and long phosphorescence of SrAl_2O_4:Eu, Dy[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2003(1/2):221-231. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%