采用化学气相沉积的方法,以锌粉、硝酸铜为原料,在硅衬底上制备了铜锌合金微米杆.用X射线衍射(XRD)、扫描电子显微镜(SEM)和X射线能谱(EDS)对沉积产物的结构、形貌和成分进行了测试与表征.结果表明,生长的铜锌合金微米杆为金属间化合物Cu3Zn合金,为立方相结构,直径在0.1 ～5 μm之间,长度可达3～30μm.锌在铜锌合金微米杆的生长中起着至关重要的作用.铜锌合金微米杆的生长属于气固反应诱导下的气液固(VLS)生长机制,与经典的气液固(VLS)生长机制具有明显不同的特点.
参考文献
| [1] | Chakarvarti SK.;Vetter J. .Template synthesis - A membrane based technology for generation of nano-/micro materials: A review[J].Radiation measurements,1998(2):149-159. |
| [2] | JAYA SARKAR;GOBINDA GOPAL KHAN;A BASUMALLICK .Nanowires: properties, applications and synthesis via porous anodic aluminium oxide template[J].Bulletin of Materials Science,2007(3):271-290. |
| [3] | Fernando Patolsky;Charles M. Lieber .Nanowire nanosensors[J].Materials Today,2005(4):20-28. |
| [4] | R. Fathi;S. Sanjabi;N. Bayat .Synthesis and characterization of NiMn alloy nanowires via electrodeposition in AAO template[J].Materials Letters,2012(1):346-348. |
| [5] | P.H. Zhou;L.J. Deng;J.L. Xie .Nanocrystalline structure and particle size effect on microwave permeability of FeNi powders prepared by mechanical alloying[J].Journal of Magnetism and Magnetic Materials,2005(0):325-331. |
| [6] | GONG Xiao-zhong,TANG Jiao-ning,LI Jun-qing,LIANG Yong-kang.Preparation and characterization of La-Co alloy nanowire arrays by electrodeposition in AAO template under nonaqueous system[J].中国有色金属学会会刊（英文版）,2008(03):642-647. |
| [7] | 马可,贺永宁,张松昌,刘卫华.宽温区内ZnO纳米线的CVD可控生长方法研究[J].人工晶体学报,2012(04):863-867,876. |
| [8] | 梁建,王晓宁,张华,刘海瑞,王晓斌,许并社.Zn掺杂Z形GaN纳米线的制备及表征[J].人工晶体学报,2012(01):36-41,46. |
| [9] | Eustis, S.;Meier, D.C.;Beversluis, M.R.;Nikoobakht, B. .Analysis of copper incorporation into zinc oxide nanowires[J].ACS nano,2008(2):368-376. |
| [10] | 季力,杨晶,李健.CeO2掺杂对ZnO薄膜气敏特性的影响[J].传感器与微系统,2011(07):60-63. |
| [11] | 熊鹏,李焕勇,介万奇,李志鹏.以CuSe纳米粒子为催化剂制备超长ZnSe纳米线[J].中国有色金属学报,2007(05):722-726. |
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