为改善锂离子电池隔膜的耐热安全性,对用于锂离子电池的ZrTiO4/PP陶瓷聚烯烃复合隔膜进行了开发研究,得到的复合膜具有高的多孔性和良好的液体电解液湿润性.膜中陶瓷具有两性特征,将电解液中的酸性副产物HF消耗掉,而HF作为现在锂离子电池所用电解液中的副产物不可避免.复合膜用于制备锂离子电池不仅具有优良的容量保持性、高温安全性,且显示出良好的倍率放电性.
参考文献
| [1] | Dong-Won Kim .Electrochemical characteristics of a carbon electrode with gel polymer electrolyte for lithium-ion polymer batteries[J].Journal of Power Sources,1998,76(02):175. |
| [2] | Kennedy B;Patterson D;Camilleri S .Use of lithium-ion batteries in electric vehicles[J].Journal of Power Sources,2000,90(02):156. |
| [3] | Izuchi S;Ochiai S;Takeuchi K .Solid polymer electrolytes for lithium cells[J].Journal of Power Sources,1997,68(01):37. |
| [4] | Brandrup J;Immergut E H.Polymer Handbook[M].New York:John Wiley and Sons,Inc,1989 |
| [5] | Y. S. Chung;S. H. Yoo;C. K. Kim .Enhancement of Meltdown Temperature of the Polyethylene Lithium-Ion Battery Separator via Surface Coating with Polymers Having High Thermal Resistance[J].Industrial & Engineering Chemistry Research,2009(9):4346-4351. |
| [6] | Yoo S H;Kim C K .Enhancement of the melt mown temperature of a lithium ion battery separator via a nano composite coating[J].Industrial & Engineering Chemistry Research,2009,48(22):9936. |
| [7] | Moon S .The effect of polymer blending and extension conditions on the properties of separator prepared by wet process for li ion secondary battery[J].Polymer (Korea),2002,26(01):45. |
| [8] | Xiao Q;Li Z;Gao D et al.A novel sandwiched membrane as polymer electrolyte for application in lithium ion battery[J].Journal of Membrane Science,2009,326(02):260. |
| [9] | P. Kritzer .Nonwoven support material for improved separators in Li-polymer batteries[J].Journal of Power Sources,2006(2):1335-1340. |
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