采用CVD法在Ni丝上直接沉积碳纳米管,并应用二极管结构对其场发射性能进行测试,测试结果表明:(1)碳管表面态对其场发射稳定性影响明显,运用密度泛函平面波赝势方法(PWP)和广义梯度近似(GGA)对碳管表面吸附水分子前后电子能带结构和态密度作比较,发现吸附水分子后碳管功函数降低,费米能级处电子态密度增大,有利于增大碳管场发射电流;(2)高真空是获得碳管场发射稳定性一个必要条件;(3)荧光粉对碳管场发射电流也有一定贡献,但大的场发射电流情形下可忽略其影响.
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